skip to main content
DOE Data Explorer title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Materials Data on Sb4I2O5 by Materials Project

Abstract

Sb4O5I2 crystallizes in the monoclinic P2_1/c space group. The structure is three-dimensional. there are two inequivalent Sb3+ sites. In the first Sb3+ site, Sb3+ is bonded in a 3-coordinate geometry to three O2- and two equivalent I1- atoms. There are a spread of Sb–O bond distances ranging from 2.02–2.09 Å. There are one shorter (3.26 Å) and one longer (3.56 Å) Sb–I bond lengths. In the second Sb3+ site, Sb3+ is bonded in a 4-coordinate geometry to four O2- and two equivalent I1- atoms. There are a spread of Sb–O bond distances ranging from 1.95–2.51 Å. There are one shorter (3.50 Å) and one longer (3.56 Å) Sb–I bond lengths. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted trigonal planar geometry to three Sb3+ atoms. In the second O2- site, O2- is bonded in a 3-coordinate geometry to three Sb3+ atoms. In the third O2- site, O2- is bonded in a linear geometry to two equivalent Sb3+ atoms. I1- is bonded in a 8-coordinate geometry to four Sb3+ atoms.

Publication Date:
Other Number(s):
mp-772282
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; Sb4I2O5; I-O-Sb
OSTI Identifier:
1301155
DOI:
10.17188/1301155

Citation Formats

The Materials Project. Materials Data on Sb4I2O5 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1301155.
The Materials Project. Materials Data on Sb4I2O5 by Materials Project. United States. doi:10.17188/1301155.
The Materials Project. 2020. "Materials Data on Sb4I2O5 by Materials Project". United States. doi:10.17188/1301155. https://www.osti.gov/servlets/purl/1301155. Pub date:Wed Jul 15 00:00:00 EDT 2020
@article{osti_1301155,
title = {Materials Data on Sb4I2O5 by Materials Project},
author = {The Materials Project},
abstractNote = {Sb4O5I2 crystallizes in the monoclinic P2_1/c space group. The structure is three-dimensional. there are two inequivalent Sb3+ sites. In the first Sb3+ site, Sb3+ is bonded in a 3-coordinate geometry to three O2- and two equivalent I1- atoms. There are a spread of Sb–O bond distances ranging from 2.02–2.09 Å. There are one shorter (3.26 Å) and one longer (3.56 Å) Sb–I bond lengths. In the second Sb3+ site, Sb3+ is bonded in a 4-coordinate geometry to four O2- and two equivalent I1- atoms. There are a spread of Sb–O bond distances ranging from 1.95–2.51 Å. There are one shorter (3.50 Å) and one longer (3.56 Å) Sb–I bond lengths. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted trigonal planar geometry to three Sb3+ atoms. In the second O2- site, O2- is bonded in a 3-coordinate geometry to three Sb3+ atoms. In the third O2- site, O2- is bonded in a linear geometry to two equivalent Sb3+ atoms. I1- is bonded in a 8-coordinate geometry to four Sb3+ atoms.},
doi = {10.17188/1301155},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}

Dataset:

Save / Share: