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Title: Materials Data on Mn(IO3)2 by Materials Project

Abstract

Mn(IO3)2 crystallizes in the orthorhombic Pbcn space group. The structure is one-dimensional and consists of two Mn(IO3)2 ribbons oriented in the (1, 0, 0) direction. Mn2+ is bonded to six O2- atoms to form edge-sharing MnO6 octahedra. There are a spread of Mn–O bond distances ranging from 2.18–2.27 Å. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted trigonal planar geometry to two equivalent Mn2+ and one I5+ atom. The O–I bond length is 1.87 Å. In the second O2- site, O2- is bonded in a distorted bent 120 degrees geometry to one Mn2+ and one I5+ atom. The O–I bond length is 1.85 Å. In the third O2- site, O2- is bonded in a distorted single-bond geometry to one I5+ atom. The O–I bond length is 1.82 Å. I5+ is bonded in a 3-coordinate geometry to three O2- atoms.

Publication Date:
Other Number(s):
mp-771047
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; Mn(IO3)2; I-Mn-O
OSTI Identifier:
1300253
DOI:
10.17188/1300253

Citation Formats

The Materials Project. Materials Data on Mn(IO3)2 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1300253.
The Materials Project. Materials Data on Mn(IO3)2 by Materials Project. United States. doi:10.17188/1300253.
The Materials Project. 2020. "Materials Data on Mn(IO3)2 by Materials Project". United States. doi:10.17188/1300253. https://www.osti.gov/servlets/purl/1300253. Pub date:Mon Aug 03 00:00:00 EDT 2020
@article{osti_1300253,
title = {Materials Data on Mn(IO3)2 by Materials Project},
author = {The Materials Project},
abstractNote = {Mn(IO3)2 crystallizes in the orthorhombic Pbcn space group. The structure is one-dimensional and consists of two Mn(IO3)2 ribbons oriented in the (1, 0, 0) direction. Mn2+ is bonded to six O2- atoms to form edge-sharing MnO6 octahedra. There are a spread of Mn–O bond distances ranging from 2.18–2.27 Å. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted trigonal planar geometry to two equivalent Mn2+ and one I5+ atom. The O–I bond length is 1.87 Å. In the second O2- site, O2- is bonded in a distorted bent 120 degrees geometry to one Mn2+ and one I5+ atom. The O–I bond length is 1.85 Å. In the third O2- site, O2- is bonded in a distorted single-bond geometry to one I5+ atom. The O–I bond length is 1.82 Å. I5+ is bonded in a 3-coordinate geometry to three O2- atoms.},
doi = {10.17188/1300253},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {8}
}

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