Materials Data on LiSbO3 by Materials Project
Abstract
LiSbO3 crystallizes in the triclinic P-1 space group. The structure is three-dimensional. Li1+ is bonded to four O2- atoms to form LiO4 tetrahedra that share corners with eight equivalent SbO6 octahedra and an edgeedge with one LiO4 tetrahedra. The corner-sharing octahedra tilt angles range from 58–62°. There are a spread of Li–O bond distances ranging from 1.98–2.16 Å. Sb5+ is bonded to six O2- atoms to form SbO6 octahedra that share corners with eight equivalent LiO4 tetrahedra and edges with three equivalent SbO6 octahedra. There are a spread of Sb–O bond distances ranging from 2.01–2.05 Å. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded to two equivalent Li1+ and two equivalent Sb5+ atoms to form distorted edge-sharing OLi2Sb2 tetrahedra. In the second O2- site, O2- is bonded in a distorted trigonal planar geometry to one Li1+ and two equivalent Sb5+ atoms. In the third O2- site, O2- is bonded in a distorted trigonal planar geometry to one Li1+ and two equivalent Sb5+ atoms.
- Authors:
- Publication Date:
- Other Number(s):
- mp-770932
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Collaborations:
- MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE
- Keywords:
- crystal structure; LiSbO3; Li-O-Sb
- OSTI Identifier:
- 1300189
- DOI:
- https://doi.org/10.17188/1300189
Citation Formats
The Materials Project. Materials Data on LiSbO3 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1300189.
The Materials Project. Materials Data on LiSbO3 by Materials Project. United States. doi:https://doi.org/10.17188/1300189
The Materials Project. 2020.
"Materials Data on LiSbO3 by Materials Project". United States. doi:https://doi.org/10.17188/1300189. https://www.osti.gov/servlets/purl/1300189. Pub date:Sat May 02 00:00:00 EDT 2020
@article{osti_1300189,
title = {Materials Data on LiSbO3 by Materials Project},
author = {The Materials Project},
abstractNote = {LiSbO3 crystallizes in the triclinic P-1 space group. The structure is three-dimensional. Li1+ is bonded to four O2- atoms to form LiO4 tetrahedra that share corners with eight equivalent SbO6 octahedra and an edgeedge with one LiO4 tetrahedra. The corner-sharing octahedra tilt angles range from 58–62°. There are a spread of Li–O bond distances ranging from 1.98–2.16 Å. Sb5+ is bonded to six O2- atoms to form SbO6 octahedra that share corners with eight equivalent LiO4 tetrahedra and edges with three equivalent SbO6 octahedra. There are a spread of Sb–O bond distances ranging from 2.01–2.05 Å. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded to two equivalent Li1+ and two equivalent Sb5+ atoms to form distorted edge-sharing OLi2Sb2 tetrahedra. In the second O2- site, O2- is bonded in a distorted trigonal planar geometry to one Li1+ and two equivalent Sb5+ atoms. In the third O2- site, O2- is bonded in a distorted trigonal planar geometry to one Li1+ and two equivalent Sb5+ atoms.},
doi = {10.17188/1300189},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {5}
}