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Title: Materials Data on Li3MnO3 by Materials Project

Abstract

Li3MnO3 is Ilmenite-like structured and crystallizes in the triclinic P1 space group. The structure is three-dimensional. there are thirty-six inequivalent Li1+ sites. In the first Li1+ site, Li1+ is bonded to four O2- atoms to form distorted LiO4 tetrahedra that share corners with four MnO6 octahedra, corners with six LiO4 tetrahedra, edges with two MnO6 octahedra, and edges with three LiO4 tetrahedra. The corner-sharing octahedra tilt angles range from 24–65°. There are a spread of Li–O bond distances ranging from 1.95–2.04 Å. In the second Li1+ site, Li1+ is bonded to four O2- atoms to form LiO4 tetrahedra that share corners with four MnO6 octahedra, corners with six LiO4 tetrahedra, edges with two MnO6 octahedra, and edges with three LiO4 tetrahedra. The corner-sharing octahedra tilt angles range from 26–56°. There are a spread of Li–O bond distances ranging from 1.96–2.03 Å. In the third Li1+ site, Li1+ is bonded to four O2- atoms to form distorted LiO4 tetrahedra that share corners with four MnO6 octahedra, corners with six LiO4 tetrahedra, edges with two MnO6 octahedra, and edges with three LiO4 tetrahedra. The corner-sharing octahedra tilt angles range from 27–56°. There are a spread of Li–O bond distances ranging from 1.87–2.07more » Å. In the fourth Li1+ site, Li1+ is bonded to four O2- atoms to form distorted LiO4 tetrahedra that share corners with four MnO6 octahedra, corners with six LiO4 tetrahedra, edges with two MnO6 octahedra, and edges with three LiO4 tetrahedra. The corner-sharing octahedra tilt angles range from 24–57°. There are a spread of Li–O bond distances ranging from 1.94–2.06 Å. In the fifth Li1+ site, Li1+ is bonded to four O2- atoms to form distorted LiO4 tetrahedra that share corners with four MnO6 octahedra, corners with six LiO4 tetrahedra, edges with two MnO6 octahedra, and edges with three LiO4 tetrahedra. The corner-sharing octahedra tilt angles range from 24–56°. There are a spread of Li–O bond distances ranging from 1.94–2.05 Å. In the sixth Li1+ site, Li1+ is bonded to four O2- atoms to form distorted LiO4 tetrahedra that share corners with four MnO6 octahedra, corners with six LiO4 tetrahedra, edges with two MnO6 octahedra, and edges with three LiO4 tetrahedra. The corner-sharing octahedra tilt angles range from 27–55°. There are a spread of Li–O bond distances ranging from 1.88–2.07 Å. In the seventh Li1+ site, Li1+ is bonded to four O2- atoms to form LiO4 tetrahedra that share corners with four MnO6 octahedra, corners with six LiO4 tetrahedra, edges with two MnO6 octahedra, and edges with three LiO4 tetrahedra. The corner-sharing octahedra tilt angles range from 26–56°. There are a spread of Li–O bond distances ranging from 1.96–2.03 Å. In the eighth Li1+ site, Li1+ is bonded to four O2- atoms to form distorted LiO4 tetrahedra that share corners with four MnO6 octahedra, corners with six LiO4 tetrahedra, edges with two MnO6 octahedra, and edges with three LiO4 tetrahedra. The corner-sharing octahedra tilt angles range from 24–65°. There are a spread of Li–O bond distances ranging from 1.95–2.04 Å. In the ninth Li1+ site, Li1+ is bonded to four O2- atoms to form distorted LiO4 tetrahedra that share corners with four MnO6 octahedra, corners with six LiO4 tetrahedra, edges with two MnO6 octahedra, and edges with three LiO4 tetrahedra. The corner-sharing octahedra tilt angles range from 27–55°. There are a spread of Li–O bond distances ranging from 1.87–2.06 Å. In the tenth Li1+ site, Li1+ is bonded to four O2- atoms to form distorted LiO4 tetrahedra that share corners with four MnO6 octahedra, corners with six LiO4 tetrahedra, edges with two MnO6 octahedra, and edges with three LiO4 tetrahedra. The corner-sharing octahedra tilt angles range from 25–56°. There are a spread of Li–O bond distances ranging from 1.94–2.05 Å. In the eleventh Li1+ site, Li1+ is bonded to four O2- atoms to form distorted LiO4 tetrahedra that share corners with four MnO6 octahedra, corners with six LiO4 tetrahedra, edges with two MnO6 octahedra, and edges with three LiO4 tetrahedra. The corner-sharing octahedra tilt angles range from 24–65°. There are a spread of Li–O bond distances ranging from 1.95–2.04 Å. In the twelfth Li1+ site, Li1+ is bonded to four O2- atoms to form LiO4 tetrahedra that share corners with four MnO6 octahedra, corners with six LiO4 tetrahedra, edges with two MnO6 octahedra, and edges with three LiO4 tetrahedra. The corner-sharing octahedra tilt angles range from 26–55°. There are a spread of Li–O bond distances ranging from 1.96–2.03 Å. In the thirteenth Li1+ site, Li1+ is bonded to four O2- atoms to form distorted LiO4 tetrahedra that share corners with four MnO6 octahedra, corners with six LiO4 tetrahedra, edges with two MnO6 octahedra, and edges with three LiO4 tetrahedra. The corner-sharing octahedra tilt angles range from 26–57°. There are a spread of Li–O bond distances ranging from 1.94–2.04 Å. In the fourteenth Li1+ site, Li1+ is bonded to four O2- atoms to form distorted LiO4 tetrahedra that share corners with four MnO6 octahedra, corners with six LiO4 tetrahedra, edges with two MnO6 octahedra, and edges with three LiO4 tetrahedra. The corner-sharing octahedra tilt angles range from 24–57°. There are a spread of Li–O bond distances ranging from 1.94–2.06 Å. In the fifteenth Li1+ site, Li1+ is bonded to four O2- atoms to form LiO4 tetrahedra that share corners with four MnO6 octahedra, corners with six LiO4 tetrahedra, edges with two MnO6 octahedra, and edges with three LiO4 tetrahedra. The corner-sharing octahedra tilt angles range from 26–56°. There are a spread of Li–O bond distances ranging from 1.94–2.03 Å. In the sixteenth Li1+ site, Li1+ is bonded to four O2- atoms to form LiO4 tetrahedra that share corners with four MnO6 octahedra, corners with six LiO4 tetrahedra, edges with two MnO6 octahedra, and edges with three LiO4 tetrahedra. The corner-sharing octahedra tilt angles range from 25–56°. There are a spread of Li–O bond distances ranging from 1.93–2.03 Å. In the seventeenth Li1+ site, Li1+ is bonded to four O2- atoms to form distorted LiO4 tetrahedra that share corners with four MnO6 octahedra, corners with six LiO4 tetrahedra, edges with two MnO6 octahedra, and edges with three LiO4 tetrahedra. The corner-sharing octahedra tilt angles range from 27–55°. There are a spread of Li–O bond distances ranging from 1.88–2.07 Å. In the eighteenth Li1+ site, Li1+ is bonded to four O2- atoms to form distorted LiO4 tetrahedra that share corners with four MnO6 octahedra, corners with six LiO4 tetrahedra, edges with two MnO6 octahedra, and edges with three LiO4 tetrahedra. The corner-sharing octahedra tilt angles range from 26–58°. There are a spread of Li–O bond distances ranging from 1.94–2.05 Å. In the nineteenth Li1+ site, Li1+ is bonded to four O2- atoms to form LiO4 tetrahedra that share corners with four MnO6 octahedra, corners with six LiO4 tetrahedra, edges with two MnO6 octahedra, and edges with three LiO4 tetrahedra. The corner-sharing octahedra tilt angles range from 26–56°. There are a spread of Li–O bond distances ranging from 1.93–2.03 Å. In the twentieth Li1+ site, Li1+ is bonded to four O2- atoms to form distorted LiO4 tetrahedra that share corners with four MnO6 octahedra, corners with six LiO4 tetrahedra, edges with two MnO6 octahedra, and edges with three LiO4 tetrahedra. The corner-sharing octahedra tilt angles range from 26–58°. There are a spread of Li–O bond distances ranging from 1.94–2.05 Å. In the twenty-first Li1+ site, Li1+ is bonded to four O2- atoms to form distorted LiO4 tetrahedra that share corners with four MnO6 octahedra, corners with six LiO4 tetrahedra, edges with two MnO6 octahedra, and edges with three LiO4 tetrahedra. The corner-sharing octahedra tilt angles range from 24–65°. There are a spread of Li–O bond distances ranging from 1.95–2.04 Å. In the twenty-second Li1+ site, Li1+ is bonded to four O2- atoms to form distorted LiO4 tetrahedra that share corners with four MnO6 octahedra, corners with six LiO4 tetrahedra, edges with two MnO6 octahedra, and edges with three LiO4 tetrahedra. The corner-sharing octahedra tilt angles range from 27–56°. There are a spread of Li–O bond distances ranging from 1.94–2.04 Å. In the twenty-third Li1+ site, Li1+ is bonded to four O2- atoms to form LiO4 tetrahedra that share corners with four MnO6 octahedra, corners with six LiO4 tetrahedra, edges with two MnO6 octahedra, and edges with three LiO4 tetrahedra. The corner-sharing octahedra tilt angles range from 26–56°. There are a spread of Li–O bond distances ranging from 1.94–2.03 Å. In the twenty-fourth Li1+ site, Li1+ is bonded to four O2- atoms to form LiO4 tetrahedra that share corners with four MnO6 octahedra, corners with six LiO4 tetrahedra, edges with two MnO6 octahedra, and edges with three LiO4 tetrahedra. The corner-sharing octahedra tilt angles range from 26–55°. There are a spread of Li–O bond distances ranging from 1.96–2.04 Å. In the twenty-fifth Li1+ site, Li1+ is bonded to four O2- atoms to form distorted LiO4 tetrahedra that share corners with four MnO6 octahedra, corners with six LiO4 tetrahedra, edges with two MnO6 octahedra, and edges with three LiO4 tetrahedra. The corner-sharing octahedra tilt angles range from 24–57°. There are a spread of Li–O bond distances ranging from 1.94–2.06 Å. In the twenty-sixth Li1+ site, Li1+ is bonded to four O2- atoms to form LiO4 tetrahedra that share corners with four MnO6 octahedra, corners with six LiO4 tetrahedra, edges with two MnO6 octahedra, and edges with three LiO4 tetrahedra. The corner-sharing octahedra tilt angles range from 26–56°. There are a spread of Li–O bond distances ranging from 1.94–2.03 Å. In the twenty-seventh Li1+ site, Li1+ is bonded to four O2- atoms to form LiO4 tetrahedra that share corners with four MnO6 octahedra, corners with six LiO4 tetrahedra, edges with two MnO6 octahedra, and edges with three LiO4 tetrahedra. The corner-sharing octahedra tilt angles range from 26–56°. There are a spread of Li–O bond distances ranging from 1.93–2.03 Å. In the twenty-eighth Li1+ site, Li1+ is bonded to four O2- atoms to form distorted LiO4 tetrahedra that share corners with four MnO6 octahedra, corners with six LiO4 tetrahedra, edges with two MnO6 octahedra, and edges with three LiO4 tetrahedra. The corner-sharing octahedra tilt angles range from 27–56°. There are a spread of Li–O bond distances ranging from 1.94–2.04 Å. In the twenty-ninth Li1+ site, Li1+ is bonded to four O2- atoms to form distorted LiO4 tetrahedra that share corners with four MnO6 octahedra, corners with six LiO4 tetrahedra, edges with two MnO6 octahedra, and edges with three LiO4 tetrahedra. The corner-sharing octahedra tilt angles range from 27–56°. There are a spread of Li–O bond distances ranging from 1.88–2.07 Å. In the thirtieth Li1+ site, Li1+ is bonded to four O2- atoms to form distorted LiO4 tetrahedra that share corners with four MnO6 octahedra, corners with six LiO4 tetrahedra, edges with two MnO6 octahedra, and edges with three LiO4 tetrahedra. The corner-sharing octahedra tilt angles range from 26–58°. There are a spread of Li–O bond distances ranging from 1.94–2.05 Å. In the thirty-first Li1+ site, Li1+ is bonded to four O2- atoms to form distorted LiO4 tetrahedra that share corners with four MnO6 octahedra, corners with six LiO4 tetrahedra, edges with two MnO6 octahedra, and edges with three LiO4 tetrahedra. The corner-sharing octahedra tilt angles range from 24–55°. There are a spread of Li–O bond distances ranging from 1.94–2.05 Å. In the thirty-second Li1+ site, Li1+ is bonded to four O2- atoms to form LiO4 tetrahedra that share corners with four MnO6 octahedra, corners with six LiO4 tetrahedra, edges with two MnO6 octahedra, and edges with three LiO4 tetrahedra. The corner-sharing octahedra tilt angles range from 26–55°. There are a spread of Li–O bond distances ranging from 1.96–2.03 Å. In the thirty-third Li1+ site, Li1+ is bonded to four O2- atoms« less

Authors:
Publication Date:
Other Number(s):
mp-770556
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Collaborations:
MIT; UC Berkeley; Duke; U Louvain
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; Li3MnO3; Li-Mn-O
OSTI Identifier:
1299873
DOI:
https://doi.org/10.17188/1299873

Citation Formats

The Materials Project. Materials Data on Li3MnO3 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1299873.
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The Materials Project. Materials Data on Li3MnO3 by Materials Project. United States. doi:https://doi.org/10.17188/1299873
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The Materials Project. 2020. "Materials Data on Li3MnO3 by Materials Project". United States. doi:https://doi.org/10.17188/1299873. https://www.osti.gov/servlets/purl/1299873. Pub date:Sat May 02 00:00:00 EDT 2020
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@article{osti_1299873,
title = {Materials Data on Li3MnO3 by Materials Project},
author = {The Materials Project},
abstractNote = {Li3MnO3 is Ilmenite-like structured and crystallizes in the triclinic P1 space group. The structure is three-dimensional. there are thirty-six inequivalent Li1+ sites. In the first Li1+ site, Li1+ is bonded to four O2- atoms to form distorted LiO4 tetrahedra that share corners with four MnO6 octahedra, corners with six LiO4 tetrahedra, edges with two MnO6 octahedra, and edges with three LiO4 tetrahedra. The corner-sharing octahedra tilt angles range from 24–65°. There are a spread of Li–O bond distances ranging from 1.95–2.04 Å. In the second Li1+ site, Li1+ is bonded to four O2- atoms to form LiO4 tetrahedra that share corners with four MnO6 octahedra, corners with six LiO4 tetrahedra, edges with two MnO6 octahedra, and edges with three LiO4 tetrahedra. The corner-sharing octahedra tilt angles range from 26–56°. There are a spread of Li–O bond distances ranging from 1.96–2.03 Å. In the third Li1+ site, Li1+ is bonded to four O2- atoms to form distorted LiO4 tetrahedra that share corners with four MnO6 octahedra, corners with six LiO4 tetrahedra, edges with two MnO6 octahedra, and edges with three LiO4 tetrahedra. The corner-sharing octahedra tilt angles range from 27–56°. There are a spread of Li–O bond distances ranging from 1.87–2.07 Å. In the fourth Li1+ site, Li1+ is bonded to four O2- atoms to form distorted LiO4 tetrahedra that share corners with four MnO6 octahedra, corners with six LiO4 tetrahedra, edges with two MnO6 octahedra, and edges with three LiO4 tetrahedra. The corner-sharing octahedra tilt angles range from 24–57°. There are a spread of Li–O bond distances ranging from 1.94–2.06 Å. In the fifth Li1+ site, Li1+ is bonded to four O2- atoms to form distorted LiO4 tetrahedra that share corners with four MnO6 octahedra, corners with six LiO4 tetrahedra, edges with two MnO6 octahedra, and edges with three LiO4 tetrahedra. The corner-sharing octahedra tilt angles range from 24–56°. There are a spread of Li–O bond distances ranging from 1.94–2.05 Å. In the sixth Li1+ site, Li1+ is bonded to four O2- atoms to form distorted LiO4 tetrahedra that share corners with four MnO6 octahedra, corners with six LiO4 tetrahedra, edges with two MnO6 octahedra, and edges with three LiO4 tetrahedra. The corner-sharing octahedra tilt angles range from 27–55°. There are a spread of Li–O bond distances ranging from 1.88–2.07 Å. In the seventh Li1+ site, Li1+ is bonded to four O2- atoms to form LiO4 tetrahedra that share corners with four MnO6 octahedra, corners with six LiO4 tetrahedra, edges with two MnO6 octahedra, and edges with three LiO4 tetrahedra. The corner-sharing octahedra tilt angles range from 26–56°. There are a spread of Li–O bond distances ranging from 1.96–2.03 Å. In the eighth Li1+ site, Li1+ is bonded to four O2- atoms to form distorted LiO4 tetrahedra that share corners with four MnO6 octahedra, corners with six LiO4 tetrahedra, edges with two MnO6 octahedra, and edges with three LiO4 tetrahedra. The corner-sharing octahedra tilt angles range from 24–65°. There are a spread of Li–O bond distances ranging from 1.95–2.04 Å. In the ninth Li1+ site, Li1+ is bonded to four O2- atoms to form distorted LiO4 tetrahedra that share corners with four MnO6 octahedra, corners with six LiO4 tetrahedra, edges with two MnO6 octahedra, and edges with three LiO4 tetrahedra. The corner-sharing octahedra tilt angles range from 27–55°. There are a spread of Li–O bond distances ranging from 1.87–2.06 Å. In the tenth Li1+ site, Li1+ is bonded to four O2- atoms to form distorted LiO4 tetrahedra that share corners with four MnO6 octahedra, corners with six LiO4 tetrahedra, edges with two MnO6 octahedra, and edges with three LiO4 tetrahedra. The corner-sharing octahedra tilt angles range from 25–56°. There are a spread of Li–O bond distances ranging from 1.94–2.05 Å. In the eleventh Li1+ site, Li1+ is bonded to four O2- atoms to form distorted LiO4 tetrahedra that share corners with four MnO6 octahedra, corners with six LiO4 tetrahedra, edges with two MnO6 octahedra, and edges with three LiO4 tetrahedra. The corner-sharing octahedra tilt angles range from 24–65°. There are a spread of Li–O bond distances ranging from 1.95–2.04 Å. In the twelfth Li1+ site, Li1+ is bonded to four O2- atoms to form LiO4 tetrahedra that share corners with four MnO6 octahedra, corners with six LiO4 tetrahedra, edges with two MnO6 octahedra, and edges with three LiO4 tetrahedra. The corner-sharing octahedra tilt angles range from 26–55°. There are a spread of Li–O bond distances ranging from 1.96–2.03 Å. In the thirteenth Li1+ site, Li1+ is bonded to four O2- atoms to form distorted LiO4 tetrahedra that share corners with four MnO6 octahedra, corners with six LiO4 tetrahedra, edges with two MnO6 octahedra, and edges with three LiO4 tetrahedra. The corner-sharing octahedra tilt angles range from 26–57°. There are a spread of Li–O bond distances ranging from 1.94–2.04 Å. In the fourteenth Li1+ site, Li1+ is bonded to four O2- atoms to form distorted LiO4 tetrahedra that share corners with four MnO6 octahedra, corners with six LiO4 tetrahedra, edges with two MnO6 octahedra, and edges with three LiO4 tetrahedra. The corner-sharing octahedra tilt angles range from 24–57°. There are a spread of Li–O bond distances ranging from 1.94–2.06 Å. In the fifteenth Li1+ site, Li1+ is bonded to four O2- atoms to form LiO4 tetrahedra that share corners with four MnO6 octahedra, corners with six LiO4 tetrahedra, edges with two MnO6 octahedra, and edges with three LiO4 tetrahedra. The corner-sharing octahedra tilt angles range from 26–56°. There are a spread of Li–O bond distances ranging from 1.94–2.03 Å. In the sixteenth Li1+ site, Li1+ is bonded to four O2- atoms to form LiO4 tetrahedra that share corners with four MnO6 octahedra, corners with six LiO4 tetrahedra, edges with two MnO6 octahedra, and edges with three LiO4 tetrahedra. The corner-sharing octahedra tilt angles range from 25–56°. There are a spread of Li–O bond distances ranging from 1.93–2.03 Å. In the seventeenth Li1+ site, Li1+ is bonded to four O2- atoms to form distorted LiO4 tetrahedra that share corners with four MnO6 octahedra, corners with six LiO4 tetrahedra, edges with two MnO6 octahedra, and edges with three LiO4 tetrahedra. The corner-sharing octahedra tilt angles range from 27–55°. There are a spread of Li–O bond distances ranging from 1.88–2.07 Å. In the eighteenth Li1+ site, Li1+ is bonded to four O2- atoms to form distorted LiO4 tetrahedra that share corners with four MnO6 octahedra, corners with six LiO4 tetrahedra, edges with two MnO6 octahedra, and edges with three LiO4 tetrahedra. The corner-sharing octahedra tilt angles range from 26–58°. There are a spread of Li–O bond distances ranging from 1.94–2.05 Å. In the nineteenth Li1+ site, Li1+ is bonded to four O2- atoms to form LiO4 tetrahedra that share corners with four MnO6 octahedra, corners with six LiO4 tetrahedra, edges with two MnO6 octahedra, and edges with three LiO4 tetrahedra. The corner-sharing octahedra tilt angles range from 26–56°. There are a spread of Li–O bond distances ranging from 1.93–2.03 Å. In the twentieth Li1+ site, Li1+ is bonded to four O2- atoms to form distorted LiO4 tetrahedra that share corners with four MnO6 octahedra, corners with six LiO4 tetrahedra, edges with two MnO6 octahedra, and edges with three LiO4 tetrahedra. The corner-sharing octahedra tilt angles range from 26–58°. There are a spread of Li–O bond distances ranging from 1.94–2.05 Å. In the twenty-first Li1+ site, Li1+ is bonded to four O2- atoms to form distorted LiO4 tetrahedra that share corners with four MnO6 octahedra, corners with six LiO4 tetrahedra, edges with two MnO6 octahedra, and edges with three LiO4 tetrahedra. The corner-sharing octahedra tilt angles range from 24–65°. There are a spread of Li–O bond distances ranging from 1.95–2.04 Å. In the twenty-second Li1+ site, Li1+ is bonded to four O2- atoms to form distorted LiO4 tetrahedra that share corners with four MnO6 octahedra, corners with six LiO4 tetrahedra, edges with two MnO6 octahedra, and edges with three LiO4 tetrahedra. The corner-sharing octahedra tilt angles range from 27–56°. There are a spread of Li–O bond distances ranging from 1.94–2.04 Å. In the twenty-third Li1+ site, Li1+ is bonded to four O2- atoms to form LiO4 tetrahedra that share corners with four MnO6 octahedra, corners with six LiO4 tetrahedra, edges with two MnO6 octahedra, and edges with three LiO4 tetrahedra. The corner-sharing octahedra tilt angles range from 26–56°. There are a spread of Li–O bond distances ranging from 1.94–2.03 Å. In the twenty-fourth Li1+ site, Li1+ is bonded to four O2- atoms to form LiO4 tetrahedra that share corners with four MnO6 octahedra, corners with six LiO4 tetrahedra, edges with two MnO6 octahedra, and edges with three LiO4 tetrahedra. The corner-sharing octahedra tilt angles range from 26–55°. There are a spread of Li–O bond distances ranging from 1.96–2.04 Å. In the twenty-fifth Li1+ site, Li1+ is bonded to four O2- atoms to form distorted LiO4 tetrahedra that share corners with four MnO6 octahedra, corners with six LiO4 tetrahedra, edges with two MnO6 octahedra, and edges with three LiO4 tetrahedra. The corner-sharing octahedra tilt angles range from 24–57°. There are a spread of Li–O bond distances ranging from 1.94–2.06 Å. In the twenty-sixth Li1+ site, Li1+ is bonded to four O2- atoms to form LiO4 tetrahedra that share corners with four MnO6 octahedra, corners with six LiO4 tetrahedra, edges with two MnO6 octahedra, and edges with three LiO4 tetrahedra. The corner-sharing octahedra tilt angles range from 26–56°. There are a spread of Li–O bond distances ranging from 1.94–2.03 Å. In the twenty-seventh Li1+ site, Li1+ is bonded to four O2- atoms to form LiO4 tetrahedra that share corners with four MnO6 octahedra, corners with six LiO4 tetrahedra, edges with two MnO6 octahedra, and edges with three LiO4 tetrahedra. The corner-sharing octahedra tilt angles range from 26–56°. There are a spread of Li–O bond distances ranging from 1.93–2.03 Å. In the twenty-eighth Li1+ site, Li1+ is bonded to four O2- atoms to form distorted LiO4 tetrahedra that share corners with four MnO6 octahedra, corners with six LiO4 tetrahedra, edges with two MnO6 octahedra, and edges with three LiO4 tetrahedra. The corner-sharing octahedra tilt angles range from 27–56°. There are a spread of Li–O bond distances ranging from 1.94–2.04 Å. In the twenty-ninth Li1+ site, Li1+ is bonded to four O2- atoms to form distorted LiO4 tetrahedra that share corners with four MnO6 octahedra, corners with six LiO4 tetrahedra, edges with two MnO6 octahedra, and edges with three LiO4 tetrahedra. The corner-sharing octahedra tilt angles range from 27–56°. There are a spread of Li–O bond distances ranging from 1.88–2.07 Å. In the thirtieth Li1+ site, Li1+ is bonded to four O2- atoms to form distorted LiO4 tetrahedra that share corners with four MnO6 octahedra, corners with six LiO4 tetrahedra, edges with two MnO6 octahedra, and edges with three LiO4 tetrahedra. The corner-sharing octahedra tilt angles range from 26–58°. There are a spread of Li–O bond distances ranging from 1.94–2.05 Å. In the thirty-first Li1+ site, Li1+ is bonded to four O2- atoms to form distorted LiO4 tetrahedra that share corners with four MnO6 octahedra, corners with six LiO4 tetrahedra, edges with two MnO6 octahedra, and edges with three LiO4 tetrahedra. The corner-sharing octahedra tilt angles range from 24–55°. There are a spread of Li–O bond distances ranging from 1.94–2.05 Å. In the thirty-second Li1+ site, Li1+ is bonded to four O2- atoms to form LiO4 tetrahedra that share corners with four MnO6 octahedra, corners with six LiO4 tetrahedra, edges with two MnO6 octahedra, and edges with three LiO4 tetrahedra. The corner-sharing octahedra tilt angles range from 26–55°. There are a spread of Li–O bond distances ranging from 1.96–2.03 Å. In the thirty-third Li1+ site, Li1+ is bonded to four O2- atoms},
doi = {10.17188/1299873},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {5}
}
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DOI: https://doi.org/10.17188/1299873
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