U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on RbLi2B3Sb2O9 by Materials Project
Abstract
RbLi2B3Sb2O9 crystallizes in the monoclinic P2/c space group. The structure is three-dimensional. Rb1+ is bonded in a 4-coordinate geometry to eight O2- atoms. There are a spread of Rb–O bond distances ranging from 2.91–3.49 Å. Li1+ is bonded to four O2- atoms to form distorted LiO4 tetrahedra that share a cornercorner with one LiO4 tetrahedra and corners with three equivalent SbO4 trigonal pyramids. There are a spread of Li–O bond distances ranging from 1.98–2.14 Å. There are two inequivalent B3+ sites. In the first B3+ site, B3+ is bonded in a trigonal planar geometry to three O2- atoms. There are a spread of B–O bond distances ranging from 1.37–1.42 Å. In the second B3+ site, B3+ is bonded in a trigonal planar geometry to three O2- atoms. There is one shorter (1.34 Å) and two longer (1.43 Å) B–O bond length. Sb3+ is bonded to four O2- atoms to form SbO4 trigonal pyramids that share corners with three equivalent LiO4 tetrahedra. There are a spread of Sb–O bond distances ranging from 2.03–2.30 Å. There are five inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted bent 120 degrees geometry to one Rb1+, one B3+, andmore »
- Publication Date:
- Other Number(s):
- mp-769329
- DOE Contract Number:
- AC02-05CH11231;
- Research Org.:
- LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- Collaborations:
- The Materials Project; MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE; B-Li-O-Rb-Sb; crystal structure; RbLi2B3Sb2O9
- OSTI Identifier:
- 1298716
- DOI:
- https://doi.org/10.17188/1298716
Citation Formats
Materials Data on RbLi2B3Sb2O9 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1298716.
Materials Data on RbLi2B3Sb2O9 by Materials Project. United States. doi:https://doi.org/10.17188/1298716
2020.
"Materials Data on RbLi2B3Sb2O9 by Materials Project". United States. doi:https://doi.org/10.17188/1298716. https://www.osti.gov/servlets/purl/1298716. Pub date:Thu Apr 30 20:00:00 EDT 2020
@article{osti_1298716,
title = {Materials Data on RbLi2B3Sb2O9 by Materials Project},
abstractNote = {RbLi2B3Sb2O9 crystallizes in the monoclinic P2/c space group. The structure is three-dimensional. Rb1+ is bonded in a 4-coordinate geometry to eight O2- atoms. There are a spread of Rb–O bond distances ranging from 2.91–3.49 Å. Li1+ is bonded to four O2- atoms to form distorted LiO4 tetrahedra that share a cornercorner with one LiO4 tetrahedra and corners with three equivalent SbO4 trigonal pyramids. There are a spread of Li–O bond distances ranging from 1.98–2.14 Å. There are two inequivalent B3+ sites. In the first B3+ site, B3+ is bonded in a trigonal planar geometry to three O2- atoms. There are a spread of B–O bond distances ranging from 1.37–1.42 Å. In the second B3+ site, B3+ is bonded in a trigonal planar geometry to three O2- atoms. There is one shorter (1.34 Å) and two longer (1.43 Å) B–O bond length. Sb3+ is bonded to four O2- atoms to form SbO4 trigonal pyramids that share corners with three equivalent LiO4 tetrahedra. There are a spread of Sb–O bond distances ranging from 2.03–2.30 Å. There are five inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted bent 120 degrees geometry to one Rb1+, one B3+, and one Sb3+ atom. In the second O2- site, O2- is bonded in a 4-coordinate geometry to one Rb1+, one Li1+, one B3+, and one Sb3+ atom. In the third O2- site, O2- is bonded in a 4-coordinate geometry to one Rb1+, one Li1+, one B3+, and one Sb3+ atom. In the fourth O2- site, O2- is bonded in a distorted trigonal planar geometry to one Li1+, one B3+, and one Sb3+ atom. In the fifth O2- site, O2- is bonded in a 3-coordinate geometry to two equivalent Rb1+, two equivalent Li1+, and one B3+ atom.},
doi = {10.17188/1298716},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {4}
}