skip to main content
DOE Data Explorer title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Materials Data on AgH9O5 by Materials Project

Abstract

AgH7O4H2O crystallizes in the orthorhombic P2_12_12_1 space group. The structure is three-dimensional and consists of four water molecules and one AgH7O4 framework. In the AgH7O4 framework, Ag1+ is bonded to six O2- atoms to form face-sharing AgO6 octahedra. There are a spread of Ag–O bond distances ranging from 2.47–2.61 Å. There are seven inequivalent H1+ sites. In the first H1+ site, H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.98 Å. In the second H1+ site, H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.99 Å. In the third H1+ site, H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 1.00 Å. In the fourth H1+ site, H1+ is bonded in a distorted linear geometry to two O2- atoms. There is one shorter (1.02 Å) and one longer (1.64 Å) H–O bond length. In the fifth H1+ site, H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.98 Å. In the sixth H1+ site, H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length ismore » 0.98 Å. In the seventh H1+ site, H1+ is bonded in a linear geometry to two O2- atoms. There is one shorter (1.02 Å) and one longer (1.62 Å) H–O bond length. There are four inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted water-like geometry to two equivalent Ag1+ and two H1+ atoms. In the second O2- site, O2- is bonded in a single-bond geometry to three H1+ atoms. In the third O2- site, O2- is bonded in a distorted water-like geometry to two equivalent Ag1+ and two H1+ atoms. In the fourth O2- site, O2- is bonded in a water-like geometry to two equivalent Ag1+ and two H1+ atoms.« less

Publication Date:
Other Number(s):
mp-769296
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; AgH9O5; Ag-H-O
OSTI Identifier:
1298705
DOI:
10.17188/1298705

Citation Formats

The Materials Project. Materials Data on AgH9O5 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1298705.
The Materials Project. Materials Data on AgH9O5 by Materials Project. United States. doi:10.17188/1298705.
The Materials Project. 2020. "Materials Data on AgH9O5 by Materials Project". United States. doi:10.17188/1298705. https://www.osti.gov/servlets/purl/1298705. Pub date:Sat May 02 00:00:00 EDT 2020
@article{osti_1298705,
title = {Materials Data on AgH9O5 by Materials Project},
author = {The Materials Project},
abstractNote = {AgH7O4H2O crystallizes in the orthorhombic P2_12_12_1 space group. The structure is three-dimensional and consists of four water molecules and one AgH7O4 framework. In the AgH7O4 framework, Ag1+ is bonded to six O2- atoms to form face-sharing AgO6 octahedra. There are a spread of Ag–O bond distances ranging from 2.47–2.61 Å. There are seven inequivalent H1+ sites. In the first H1+ site, H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.98 Å. In the second H1+ site, H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.99 Å. In the third H1+ site, H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 1.00 Å. In the fourth H1+ site, H1+ is bonded in a distorted linear geometry to two O2- atoms. There is one shorter (1.02 Å) and one longer (1.64 Å) H–O bond length. In the fifth H1+ site, H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.98 Å. In the sixth H1+ site, H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.98 Å. In the seventh H1+ site, H1+ is bonded in a linear geometry to two O2- atoms. There is one shorter (1.02 Å) and one longer (1.62 Å) H–O bond length. There are four inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted water-like geometry to two equivalent Ag1+ and two H1+ atoms. In the second O2- site, O2- is bonded in a single-bond geometry to three H1+ atoms. In the third O2- site, O2- is bonded in a distorted water-like geometry to two equivalent Ag1+ and two H1+ atoms. In the fourth O2- site, O2- is bonded in a water-like geometry to two equivalent Ag1+ and two H1+ atoms.},
doi = {10.17188/1298705},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {5}
}

Dataset:

Save / Share: