U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on Li2CoSiO4 by Materials Project
Abstract
Li2CoSiO4 is Stannite structured and crystallizes in the monoclinic C2 space group. The structure is three-dimensional. Li1+ is bonded to four O2- atoms to form LiO4 tetrahedra that share corners with four equivalent LiO4 tetrahedra, corners with four equivalent CoO4 tetrahedra, and corners with four equivalent SiO4 tetrahedra. There is one shorter (1.97 Å) and three longer (1.98 Å) Li–O bond length. Co2+ is bonded to four O2- atoms to form CoO4 tetrahedra that share corners with four equivalent SiO4 tetrahedra and corners with eight equivalent LiO4 tetrahedra. All Co–O bond lengths are 2.01 Å. Si4+ is bonded to four O2- atoms to form SiO4 tetrahedra that share corners with four equivalent CoO4 tetrahedra and corners with eight equivalent LiO4 tetrahedra. All Si–O bond lengths are 1.66 Å. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded to two equivalent Li1+, one Co2+, and one Si4+ atom to form corner-sharing OLi2CoSi tetrahedra. In the second O2- site, O2- is bonded to two equivalent Li1+, one Co2+, and one Si4+ atom to form corner-sharing OLi2CoSi tetrahedra.
- Publication Date:
- Other Number(s):
- mp-764642
- DOE Contract Number:
- AC02-05CH11231
- Research Org.:
- LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- Collaborations:
- The Materials Project; MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE; Co-Li-O-Si; Li2CoSiO4; crystal structure
- OSTI Identifier:
- 1295068
- DOI:
- https://doi.org/10.17188/1295068
Citation Formats
Materials Data on Li2CoSiO4 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1295068.
Materials Data on Li2CoSiO4 by Materials Project. United States. doi:https://doi.org/10.17188/1295068
2020.
"Materials Data on Li2CoSiO4 by Materials Project". United States. doi:https://doi.org/10.17188/1295068. https://www.osti.gov/servlets/purl/1295068. Pub date:Sat May 02 04:00:00 UTC 2020
@article{osti_1295068,
title = {Materials Data on Li2CoSiO4 by Materials Project},
abstractNote = {Li2CoSiO4 is Stannite structured and crystallizes in the monoclinic C2 space group. The structure is three-dimensional. Li1+ is bonded to four O2- atoms to form LiO4 tetrahedra that share corners with four equivalent LiO4 tetrahedra, corners with four equivalent CoO4 tetrahedra, and corners with four equivalent SiO4 tetrahedra. There is one shorter (1.97 Å) and three longer (1.98 Å) Li–O bond length. Co2+ is bonded to four O2- atoms to form CoO4 tetrahedra that share corners with four equivalent SiO4 tetrahedra and corners with eight equivalent LiO4 tetrahedra. All Co–O bond lengths are 2.01 Å. Si4+ is bonded to four O2- atoms to form SiO4 tetrahedra that share corners with four equivalent CoO4 tetrahedra and corners with eight equivalent LiO4 tetrahedra. All Si–O bond lengths are 1.66 Å. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded to two equivalent Li1+, one Co2+, and one Si4+ atom to form corner-sharing OLi2CoSi tetrahedra. In the second O2- site, O2- is bonded to two equivalent Li1+, one Co2+, and one Si4+ atom to form corner-sharing OLi2CoSi tetrahedra.},
doi = {10.17188/1295068},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {5}
}