Materials Data on Li2CoSiO4 by Materials Project
Abstract
Li2CoSiO4 crystallizes in the trigonal P3_121 space group. The structure is three-dimensional. Li1+ is bonded to four O2- atoms to form LiO4 tetrahedra that share corners with four equivalent LiO4 tetrahedra and corners with four equivalent SiO4 tetrahedra. There are a spread of Li–O bond distances ranging from 1.94–2.05 Å. Co2+ is bonded in a distorted square co-planar geometry to four O2- atoms. There are two shorter (2.00 Å) and two longer (2.04 Å) Co–O bond lengths. Si4+ is bonded to four O2- atoms to form SiO4 tetrahedra that share corners with eight equivalent LiO4 tetrahedra. All Si–O bond lengths are 1.65 Å. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded to two equivalent Li1+, one Co2+, and one Si4+ atom to form a mixture of distorted edge and corner-sharing OLi2CoSi tetrahedra. In the second O2- site, O2- is bonded to two equivalent Li1+, one Co2+, and one Si4+ atom to form a mixture of distorted edge and corner-sharing OLi2CoSi tetrahedra.
- Authors:
- Publication Date:
- Other Number(s):
- mp-762264
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Collaborations:
- MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE
- Keywords:
- crystal structure; Li2CoSiO4; Co-Li-O-Si
- OSTI Identifier:
- 1292529
- DOI:
- https://doi.org/10.17188/1292529
Citation Formats
The Materials Project. Materials Data on Li2CoSiO4 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1292529.
The Materials Project. Materials Data on Li2CoSiO4 by Materials Project. United States. doi:https://doi.org/10.17188/1292529
The Materials Project. 2020.
"Materials Data on Li2CoSiO4 by Materials Project". United States. doi:https://doi.org/10.17188/1292529. https://www.osti.gov/servlets/purl/1292529. Pub date:Thu Jun 04 00:00:00 EDT 2020
@article{osti_1292529,
title = {Materials Data on Li2CoSiO4 by Materials Project},
author = {The Materials Project},
abstractNote = {Li2CoSiO4 crystallizes in the trigonal P3_121 space group. The structure is three-dimensional. Li1+ is bonded to four O2- atoms to form LiO4 tetrahedra that share corners with four equivalent LiO4 tetrahedra and corners with four equivalent SiO4 tetrahedra. There are a spread of Li–O bond distances ranging from 1.94–2.05 Å. Co2+ is bonded in a distorted square co-planar geometry to four O2- atoms. There are two shorter (2.00 Å) and two longer (2.04 Å) Co–O bond lengths. Si4+ is bonded to four O2- atoms to form SiO4 tetrahedra that share corners with eight equivalent LiO4 tetrahedra. All Si–O bond lengths are 1.65 Å. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded to two equivalent Li1+, one Co2+, and one Si4+ atom to form a mixture of distorted edge and corner-sharing OLi2CoSi tetrahedra. In the second O2- site, O2- is bonded to two equivalent Li1+, one Co2+, and one Si4+ atom to form a mixture of distorted edge and corner-sharing OLi2CoSi tetrahedra.},
doi = {10.17188/1292529},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Thu Jun 04 00:00:00 EDT 2020},
month = {Thu Jun 04 00:00:00 EDT 2020}
}