U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on Mn(CO3)2 by Materials Project
Abstract
Mn(CO3)2 crystallizes in the monoclinic P2_1/c space group. The structure is two-dimensional and consists of one Mn(CO3)2 sheet oriented in the (1, 0, 0) direction. Mn4+ is bonded in an octahedral geometry to six O2- atoms. There are a spread of Mn–O bond distances ranging from 1.93–1.99 Å. C4+ is bonded in a trigonal planar geometry to three O2- atoms. There is one shorter (1.28 Å) and two longer (1.30 Å) C–O bond length. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded in an L-shaped geometry to one Mn4+ and one C4+ atom. In the second O2- site, O2- is bonded in an L-shaped geometry to one Mn4+ and one C4+ atom. In the third O2- site, O2- is bonded in a bent 120 degrees geometry to one Mn4+ and one C4+ atom.
- Publication Date:
- Other Number(s):
- mp-762239
- DOE Contract Number:
- AC02-05CH11231
- Research Org.:
- LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- Collaborations:
- The Materials Project; MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE; C-Mn-O; Mn(CO3)2; crystal structure
- OSTI Identifier:
- 1292512
- DOI:
- https://doi.org/10.17188/1292512
Citation Formats
Materials Data on Mn(CO3)2 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1292512.
Materials Data on Mn(CO3)2 by Materials Project. United States. doi:https://doi.org/10.17188/1292512
2020.
"Materials Data on Mn(CO3)2 by Materials Project". United States. doi:https://doi.org/10.17188/1292512. https://www.osti.gov/servlets/purl/1292512. Pub date:Wed Apr 29 00:00:00 EDT 2020
@article{osti_1292512,
title = {Materials Data on Mn(CO3)2 by Materials Project},
abstractNote = {Mn(CO3)2 crystallizes in the monoclinic P2_1/c space group. The structure is two-dimensional and consists of one Mn(CO3)2 sheet oriented in the (1, 0, 0) direction. Mn4+ is bonded in an octahedral geometry to six O2- atoms. There are a spread of Mn–O bond distances ranging from 1.93–1.99 Å. C4+ is bonded in a trigonal planar geometry to three O2- atoms. There is one shorter (1.28 Å) and two longer (1.30 Å) C–O bond length. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded in an L-shaped geometry to one Mn4+ and one C4+ atom. In the second O2- site, O2- is bonded in an L-shaped geometry to one Mn4+ and one C4+ atom. In the third O2- site, O2- is bonded in a bent 120 degrees geometry to one Mn4+ and one C4+ atom.},
doi = {10.17188/1292512},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {4}
}