U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on Li2AgF3 by Materials Project
Abstract
Li2AgF3 crystallizes in the orthorhombic Cmcm space group. The structure is three-dimensional. Li1+ is bonded to six F1- atoms to form a mixture of distorted edge, face, and corner-sharing LiF6 octahedra. The corner-sharing octahedra tilt angles range from 18–26°. There are a spread of Li–F bond distances ranging from 2.06–2.20 Å. Ag1+ is bonded in a trigonal planar geometry to three F1- atoms. There are one shorter (2.26 Å) and two longer (2.29 Å) Ag–F bond lengths. There are two inequivalent F1- sites. In the first F1- site, F1- is bonded in a 5-coordinate geometry to four equivalent Li1+ and one Ag1+ atom. In the second F1- site, F1- is bonded to four equivalent Li1+ and one Ag1+ atom to form distorted edge-sharing FLi4Ag square pyramids.
- Publication Date:
- Other Number(s):
- mp-759198
- DOE Contract Number:
- AC02-05CH11231
- Research Org.:
- LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- Collaborations:
- The Materials Project; MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE; Ag-F-Li; Li2AgF3; crystal structure
- OSTI Identifier:
- 1291360
- DOI:
- https://doi.org/10.17188/1291360
Citation Formats
Materials Data on Li2AgF3 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1291360.
Materials Data on Li2AgF3 by Materials Project. United States. doi:https://doi.org/10.17188/1291360
2020.
"Materials Data on Li2AgF3 by Materials Project". United States. doi:https://doi.org/10.17188/1291360. https://www.osti.gov/servlets/purl/1291360. Pub date:Sat May 02 00:00:00 EDT 2020
@article{osti_1291360,
title = {Materials Data on Li2AgF3 by Materials Project},
abstractNote = {Li2AgF3 crystallizes in the orthorhombic Cmcm space group. The structure is three-dimensional. Li1+ is bonded to six F1- atoms to form a mixture of distorted edge, face, and corner-sharing LiF6 octahedra. The corner-sharing octahedra tilt angles range from 18–26°. There are a spread of Li–F bond distances ranging from 2.06–2.20 Å. Ag1+ is bonded in a trigonal planar geometry to three F1- atoms. There are one shorter (2.26 Å) and two longer (2.29 Å) Ag–F bond lengths. There are two inequivalent F1- sites. In the first F1- site, F1- is bonded in a 5-coordinate geometry to four equivalent Li1+ and one Ag1+ atom. In the second F1- site, F1- is bonded to four equivalent Li1+ and one Ag1+ atom to form distorted edge-sharing FLi4Ag square pyramids.},
doi = {10.17188/1291360},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {5}
}