U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on SbAsAuF9 by Materials Project
Abstract
AuSbF6AsF3 crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four trifluoroarsine molecules and four AuSbF6 clusters. In each AuSbF6 cluster, Au1+ is bonded in a 1-coordinate geometry to one F1- atom. The Au–F bond length is 2.17 Å. Sb3+ is bonded in an octahedral geometry to six F1- atoms. There are a spread of Sb–F bond distances ranging from 1.90–2.00 Å. There are six inequivalent F1- sites. In the first F1- site, F1- is bonded in a single-bond geometry to one Sb3+ atom. In the second F1- site, F1- is bonded in a single-bond geometry to one Sb3+ atom. In the third F1- site, F1- is bonded in a bent 120 degrees geometry to one Au1+ and one Sb3+ atom. In the fourth F1- site, F1- is bonded in a single-bond geometry to one Sb3+ atom. In the fifth F1- site, F1- is bonded in a distorted single-bond geometry to one Sb3+ atom. In the sixth F1- site, F1- is bonded in a single-bond geometry to one Sb3+ atom.
- Publication Date:
- Other Number(s):
- mp-758923
- DOE Contract Number:
- AC02-05CH11231
- Research Org.:
- LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- Collaborations:
- The Materials Project; MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE; As-Au-F-Sb; SbAsAuF9; crystal structure
- OSTI Identifier:
- 1291304
- DOI:
- https://doi.org/10.17188/1291304
Citation Formats
Materials Data on SbAsAuF9 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1291304.
Materials Data on SbAsAuF9 by Materials Project. United States. doi:https://doi.org/10.17188/1291304
2020.
"Materials Data on SbAsAuF9 by Materials Project". United States. doi:https://doi.org/10.17188/1291304. https://www.osti.gov/servlets/purl/1291304. Pub date:Thu Apr 30 04:00:00 UTC 2020
@article{osti_1291304,
title = {Materials Data on SbAsAuF9 by Materials Project},
abstractNote = {AuSbF6AsF3 crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four trifluoroarsine molecules and four AuSbF6 clusters. In each AuSbF6 cluster, Au1+ is bonded in a 1-coordinate geometry to one F1- atom. The Au–F bond length is 2.17 Å. Sb3+ is bonded in an octahedral geometry to six F1- atoms. There are a spread of Sb–F bond distances ranging from 1.90–2.00 Å. There are six inequivalent F1- sites. In the first F1- site, F1- is bonded in a single-bond geometry to one Sb3+ atom. In the second F1- site, F1- is bonded in a single-bond geometry to one Sb3+ atom. In the third F1- site, F1- is bonded in a bent 120 degrees geometry to one Au1+ and one Sb3+ atom. In the fourth F1- site, F1- is bonded in a single-bond geometry to one Sb3+ atom. In the fifth F1- site, F1- is bonded in a distorted single-bond geometry to one Sb3+ atom. In the sixth F1- site, F1- is bonded in a single-bond geometry to one Sb3+ atom.},
doi = {10.17188/1291304},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {4}
}