U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on Sb8Cl2O11 by Materials Project
Abstract
Sb8O11Cl2 crystallizes in the monoclinic P2_1/c space group. The structure is two-dimensional and consists of one Sb8O11Cl2 sheet oriented in the (1, 0, 0) direction. there are four inequivalent Sb3+ sites. In the first Sb3+ site, Sb3+ is bonded in a 2-coordinate geometry to two O2- and one Cl1- atom. There are one shorter (1.98 Å) and one longer (2.02 Å) Sb–O bond lengths. The Sb–Cl bond length is 2.57 Å. In the second Sb3+ site, Sb3+ is bonded in a distorted T-shaped geometry to three O2- atoms. All Sb–O bond lengths are 2.01 Å. In the third Sb3+ site, Sb3+ is bonded in a distorted square co-planar geometry to four O2- atoms. There are a spread of Sb–O bond distances ranging from 2.01–2.26 Å. In the fourth Sb3+ site, Sb3+ is bonded in a rectangular see-saw-like geometry to four O2- atoms. There are a spread of Sb–O bond distances ranging from 2.01–2.23 Å. There are six inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted bent 150 degrees geometry to two Sb3+ atoms. In the second O2- site, O2- is bonded in a bent 120 degrees geometry to two Sb3+ atoms. In the thirdmore »
- Authors:
- Publication Date:
- Other Number(s):
- mp-758203
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Collaborations:
- MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE
- Keywords:
- crystal structure; Sb8Cl2O11; Cl-O-Sb
- OSTI Identifier:
- 1291018
- DOI:
- https://doi.org/10.17188/1291018
Citation Formats
The Materials Project. Materials Data on Sb8Cl2O11 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1291018.
The Materials Project. Materials Data on Sb8Cl2O11 by Materials Project. United States. doi:https://doi.org/10.17188/1291018
The Materials Project. 2020.
"Materials Data on Sb8Cl2O11 by Materials Project". United States. doi:https://doi.org/10.17188/1291018. https://www.osti.gov/servlets/purl/1291018. Pub date:Wed Jul 15 00:00:00 EDT 2020
@article{osti_1291018,
title = {Materials Data on Sb8Cl2O11 by Materials Project},
author = {The Materials Project},
abstractNote = {Sb8O11Cl2 crystallizes in the monoclinic P2_1/c space group. The structure is two-dimensional and consists of one Sb8O11Cl2 sheet oriented in the (1, 0, 0) direction. there are four inequivalent Sb3+ sites. In the first Sb3+ site, Sb3+ is bonded in a 2-coordinate geometry to two O2- and one Cl1- atom. There are one shorter (1.98 Å) and one longer (2.02 Å) Sb–O bond lengths. The Sb–Cl bond length is 2.57 Å. In the second Sb3+ site, Sb3+ is bonded in a distorted T-shaped geometry to three O2- atoms. All Sb–O bond lengths are 2.01 Å. In the third Sb3+ site, Sb3+ is bonded in a distorted square co-planar geometry to four O2- atoms. There are a spread of Sb–O bond distances ranging from 2.01–2.26 Å. In the fourth Sb3+ site, Sb3+ is bonded in a rectangular see-saw-like geometry to four O2- atoms. There are a spread of Sb–O bond distances ranging from 2.01–2.23 Å. There are six inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted bent 150 degrees geometry to two Sb3+ atoms. In the second O2- site, O2- is bonded in a bent 120 degrees geometry to two Sb3+ atoms. In the third O2- site, O2- is bonded in a distorted trigonal non-coplanar geometry to three Sb3+ atoms. In the fourth O2- site, O2- is bonded in a linear geometry to two equivalent Sb3+ atoms. In the fifth O2- site, O2- is bonded in a bent 120 degrees geometry to two Sb3+ atoms. In the sixth O2- site, O2- is bonded in a distorted trigonal non-coplanar geometry to three Sb3+ atoms. Cl1- is bonded in a single-bond geometry to one Sb3+ atom.},
doi = {10.17188/1291018},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}