U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on Li2V2S5 by Materials Project
Abstract
Li2V2S5 crystallizes in the monoclinic C2/c space group. The structure is three-dimensional. Li1+ is bonded in a 5-coordinate geometry to five S2- atoms. There are a spread of Li–S bond distances ranging from 2.50–2.83 Å. V4+ is bonded to five S2- atoms to form a mixture of distorted edge and corner-sharing VS5 trigonal bipyramids. There are a spread of V–S bond distances ranging from 2.18–2.46 Å. There are three inequivalent S2- sites. In the first S2- site, S2- is bonded in a distorted rectangular see-saw-like geometry to two equivalent Li1+ and two equivalent V4+ atoms. In the second S2- site, S2- is bonded in a distorted rectangular see-saw-like geometry to two equivalent Li1+ and two equivalent V4+ atoms. In the third S2- site, S2- is bonded in a distorted trigonal pyramidal geometry to two equivalent Li1+ and two equivalent V4+ atoms.
- Publication Date:
- Other Number(s):
- mp-756394
- DOE Contract Number:
- AC02-05CH11231
- Research Org.:
- LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- Collaborations:
- The Materials Project; MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE; Li-S-V; Li2V2S5; crystal structure
- OSTI Identifier:
- 1290497
- DOI:
- https://doi.org/10.17188/1290497
Citation Formats
Materials Data on Li2V2S5 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1290497.
Materials Data on Li2V2S5 by Materials Project. United States. doi:https://doi.org/10.17188/1290497
2020.
"Materials Data on Li2V2S5 by Materials Project". United States. doi:https://doi.org/10.17188/1290497. https://www.osti.gov/servlets/purl/1290497. Pub date:Sat May 02 04:00:00 UTC 2020
@article{osti_1290497,
title = {Materials Data on Li2V2S5 by Materials Project},
abstractNote = {Li2V2S5 crystallizes in the monoclinic C2/c space group. The structure is three-dimensional. Li1+ is bonded in a 5-coordinate geometry to five S2- atoms. There are a spread of Li–S bond distances ranging from 2.50–2.83 Å. V4+ is bonded to five S2- atoms to form a mixture of distorted edge and corner-sharing VS5 trigonal bipyramids. There are a spread of V–S bond distances ranging from 2.18–2.46 Å. There are three inequivalent S2- sites. In the first S2- site, S2- is bonded in a distorted rectangular see-saw-like geometry to two equivalent Li1+ and two equivalent V4+ atoms. In the second S2- site, S2- is bonded in a distorted rectangular see-saw-like geometry to two equivalent Li1+ and two equivalent V4+ atoms. In the third S2- site, S2- is bonded in a distorted trigonal pyramidal geometry to two equivalent Li1+ and two equivalent V4+ atoms.},
doi = {10.17188/1290497},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {5}
}