skip to main content
DOE Data Explorer title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Materials Data on AgSnO3 by Materials Project

Abstract

AgSnO3 crystallizes in the monoclinic Cm space group. The structure is three-dimensional. there are two inequivalent Ag2+ sites. In the first Ag2+ site, Ag2+ is bonded in a square co-planar geometry to four O2- atoms. There are two shorter (2.05 Å) and two longer (2.06 Å) Ag–O bond lengths. In the second Ag2+ site, Ag2+ is bonded to eight O2- atoms to form distorted AgO8 hexagonal bipyramids that share edges with two equivalent AgO8 hexagonal bipyramids and edges with eight equivalent SnO6 octahedra. There are a spread of Ag–O bond distances ranging from 2.49–2.69 Å. Sn4+ is bonded to six O2- atoms to form SnO6 octahedra that share corners with two equivalent SnO6 octahedra, edges with four equivalent AgO8 hexagonal bipyramids, and edges with two equivalent SnO6 octahedra. The corner-sharing octahedral tilt angles are 47°. There are two shorter (2.06 Å) and four longer (2.13 Å) Sn–O bond lengths. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded in a 4-coordinate geometry to two Ag2+ and two equivalent Sn4+ atoms. In the second O2- site, O2- is bonded in a 4-coordinate geometry to two equivalent Ag2+ and two equivalent Sn4+ atoms. In the third O2-more » site, O2- is bonded in a 4-coordinate geometry to two Ag2+ and two equivalent Sn4+ atoms.« less

Publication Date:
Other Number(s):
mp-755834
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; AgSnO3; Ag-O-Sn
OSTI Identifier:
1290240
DOI:
10.17188/1290240

Citation Formats

The Materials Project. Materials Data on AgSnO3 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1290240.
The Materials Project. Materials Data on AgSnO3 by Materials Project. United States. doi:10.17188/1290240.
The Materials Project. 2020. "Materials Data on AgSnO3 by Materials Project". United States. doi:10.17188/1290240. https://www.osti.gov/servlets/purl/1290240. Pub date:Thu Jul 23 00:00:00 EDT 2020
@article{osti_1290240,
title = {Materials Data on AgSnO3 by Materials Project},
author = {The Materials Project},
abstractNote = {AgSnO3 crystallizes in the monoclinic Cm space group. The structure is three-dimensional. there are two inequivalent Ag2+ sites. In the first Ag2+ site, Ag2+ is bonded in a square co-planar geometry to four O2- atoms. There are two shorter (2.05 Å) and two longer (2.06 Å) Ag–O bond lengths. In the second Ag2+ site, Ag2+ is bonded to eight O2- atoms to form distorted AgO8 hexagonal bipyramids that share edges with two equivalent AgO8 hexagonal bipyramids and edges with eight equivalent SnO6 octahedra. There are a spread of Ag–O bond distances ranging from 2.49–2.69 Å. Sn4+ is bonded to six O2- atoms to form SnO6 octahedra that share corners with two equivalent SnO6 octahedra, edges with four equivalent AgO8 hexagonal bipyramids, and edges with two equivalent SnO6 octahedra. The corner-sharing octahedral tilt angles are 47°. There are two shorter (2.06 Å) and four longer (2.13 Å) Sn–O bond lengths. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded in a 4-coordinate geometry to two Ag2+ and two equivalent Sn4+ atoms. In the second O2- site, O2- is bonded in a 4-coordinate geometry to two equivalent Ag2+ and two equivalent Sn4+ atoms. In the third O2- site, O2- is bonded in a 4-coordinate geometry to two Ag2+ and two equivalent Sn4+ atoms.},
doi = {10.17188/1290240},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}

Dataset:

Save / Share: