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Title: Materials Data on Bi2OF4 by Materials Project

Abstract

Bi2OF4 crystallizes in the monoclinic C2/c space group. The structure is three-dimensional. Bi3+ is bonded in a 8-coordinate geometry to two equivalent O2- and six F1- atoms. There are one shorter (2.34 Å) and one longer (2.35 Å) Bi–O bond lengths. There are a spread of Bi–F bond distances ranging from 2.38–2.61 Å. O2- is bonded to four equivalent Bi3+ atoms to form distorted edge-sharing OBi4 tetrahedra. There are two inequivalent F1- sites. In the first F1- site, F1- is bonded in a 3-coordinate geometry to three equivalent Bi3+ atoms. In the second F1- site, F1- is bonded in a 3-coordinate geometry to three equivalent Bi3+ atoms.

Authors:
Publication Date:
Other Number(s):
mp-753309
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Collaborations:
MIT; UC Berkeley; Duke; U Louvain
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; Bi2OF4; Bi-F-O
OSTI Identifier:
1288972
DOI:
https://doi.org/10.17188/1288972

Citation Formats

The Materials Project. Materials Data on Bi2OF4 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1288972.
The Materials Project. Materials Data on Bi2OF4 by Materials Project. United States. doi:https://doi.org/10.17188/1288972
The Materials Project. 2020. "Materials Data on Bi2OF4 by Materials Project". United States. doi:https://doi.org/10.17188/1288972. https://www.osti.gov/servlets/purl/1288972. Pub date:Sat Jul 18 00:00:00 EDT 2020
@article{osti_1288972,
title = {Materials Data on Bi2OF4 by Materials Project},
author = {The Materials Project},
abstractNote = {Bi2OF4 crystallizes in the monoclinic C2/c space group. The structure is three-dimensional. Bi3+ is bonded in a 8-coordinate geometry to two equivalent O2- and six F1- atoms. There are one shorter (2.34 Å) and one longer (2.35 Å) Bi–O bond lengths. There are a spread of Bi–F bond distances ranging from 2.38–2.61 Å. O2- is bonded to four equivalent Bi3+ atoms to form distorted edge-sharing OBi4 tetrahedra. There are two inequivalent F1- sites. In the first F1- site, F1- is bonded in a 3-coordinate geometry to three equivalent Bi3+ atoms. In the second F1- site, F1- is bonded in a 3-coordinate geometry to three equivalent Bi3+ atoms.},
doi = {10.17188/1288972},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}