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Title: Materials Data on SbO2F by Materials Project

Abstract

SbO2F crystallizes in the monoclinic Cc space group. The structure is three-dimensional. Sb5+ is bonded to four O2- and two equivalent F1- atoms to form corner-sharing SbO4F2 octahedra. The corner-sharing octahedra tilt angles range from 37–44°. There is two shorter (1.94 Å) and two longer (1.95 Å) Sb–O bond length. There are one shorter (2.11 Å) and one longer (2.16 Å) Sb–F bond lengths. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted bent 150 degrees geometry to two equivalent Sb5+ atoms. In the second O2- site, O2- is bonded in a distorted bent 150 degrees geometry to two equivalent Sb5+ atoms. F1- is bonded in a distorted bent 150 degrees geometry to two equivalent Sb5+ atoms.

Authors:
Publication Date:
Other Number(s):
mp-752561
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Collaborations:
MIT; UC Berkeley; Duke; U Louvain
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; SbO2F; F-O-Sb
OSTI Identifier:
1288695
DOI:
https://doi.org/10.17188/1288695

Citation Formats

The Materials Project. Materials Data on SbO2F by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1288695.
The Materials Project. Materials Data on SbO2F by Materials Project. United States. doi:https://doi.org/10.17188/1288695
The Materials Project. 2020. "Materials Data on SbO2F by Materials Project". United States. doi:https://doi.org/10.17188/1288695. https://www.osti.gov/servlets/purl/1288695. Pub date:Thu Jul 23 00:00:00 EDT 2020
@article{osti_1288695,
title = {Materials Data on SbO2F by Materials Project},
author = {The Materials Project},
abstractNote = {SbO2F crystallizes in the monoclinic Cc space group. The structure is three-dimensional. Sb5+ is bonded to four O2- and two equivalent F1- atoms to form corner-sharing SbO4F2 octahedra. The corner-sharing octahedra tilt angles range from 37–44°. There is two shorter (1.94 Å) and two longer (1.95 Å) Sb–O bond length. There are one shorter (2.11 Å) and one longer (2.16 Å) Sb–F bond lengths. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted bent 150 degrees geometry to two equivalent Sb5+ atoms. In the second O2- site, O2- is bonded in a distorted bent 150 degrees geometry to two equivalent Sb5+ atoms. F1- is bonded in a distorted bent 150 degrees geometry to two equivalent Sb5+ atoms.},
doi = {10.17188/1288695},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}