Materials Data on H12OsC4N(OF)3 by Materials Project

doi:10.17188/1287906

Title: Materials Data on H12OsC4N(OF)3 by Materials Project

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Abstract

Os(OF)3N(CH3)4 is Silicon tetrafluoride-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight tetramethylammonium molecules and eight Os(OF)3 clusters. In each Os(OF)3 cluster, Os2- is bonded in a distorted octahedral geometry to three O2- and three F1- atoms. All Os–O bond lengths are 1.73 Å. There are a spread of Os–F bond distances ranging from 1.99–2.01 Å. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded in a single-bond geometry to one Os2- atom. In the second O2- site, O2- is bonded in a single-bond geometry to one Os2- atom. In the third O2- site, O2- is bonded in a single-bond geometry to one Os2- atom. There are three inequivalent F1- sites. In the first F1- site, F1- is bonded in a single-bond geometry to one Os2- atom. In the second F1- site, F1- is bonded in a single-bond geometry to one Os2- atom. In the third F1- site, F1- is bonded in a single-bond geometry to one Os2- atom.

Publication Date:: 2020-05-02

Other Number(s):: mp-738695

DOE Contract Number:: AC02-05CH11231

Research Org.:: LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Collaborations:: The Materials Project; MIT; UC Berkeley; Duke; U Louvain

Subject:: 36 MATERIALS SCIENCE; C-F-H-N-O-Os; H12OsC4N(OF)3; crystal structure

OSTI Identifier:: 1287906

DOI:: https://doi.org/10.17188/1287906

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                    Materials Data on H12OsC4N(OF)3 by Materials Project.  United States: N. p., 2020. 
        Web.  doi:10.17188/1287906.

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                    Materials Data on H12OsC4N(OF)3 by Materials Project.  United States.  doi:https://doi.org/10.17188/1287906

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                    2020.  
"Materials Data on H12OsC4N(OF)3 by Materials Project".  United States.  doi:https://doi.org/10.17188/1287906.  https://www.osti.gov/servlets/purl/1287906. Pub date:Sat May 02 04:00:00 UTC 2020

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@article{osti_1287906,

  title        = {Materials Data on H12OsC4N(OF)3 by Materials Project},

  
  abstractNote = {Os(OF)3N(CH3)4 is Silicon tetrafluoride-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight tetramethylammonium molecules and eight Os(OF)3 clusters. In each Os(OF)3 cluster, Os2- is bonded in a distorted octahedral geometry to three O2- and three F1- atoms. All Os–O bond lengths are 1.73 Å. There are a spread of Os–F bond distances ranging from 1.99–2.01 Å. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded in a single-bond geometry to one Os2- atom. In the second O2- site, O2- is bonded in a single-bond geometry to one Os2- atom. In the third O2- site, O2- is bonded in a single-bond geometry to one Os2- atom. There are three inequivalent F1- sites. In the first F1- site, F1- is bonded in a single-bond geometry to one Os2- atom. In the second F1- site, F1- is bonded in a single-bond geometry to one Os2- atom. In the third F1- site, F1- is bonded in a single-bond geometry to one Os2- atom.},

  doi          = {10.17188/1287906},

  journal      = {},

  number       = ,

  volume       = ,

  place        = {United States},

  year         = {2020},

  month        = {5}

}

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DOI: https://doi.org/10.17188/1287906

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