skip to main content
DOE Data Explorer title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Materials Data on H12OsC4N(OF)3 by Materials Project

Abstract

Os(OF)3N(CH3)4 is Silicon tetrafluoride-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight tetramethylammonium molecules and eight Os(OF)3 clusters. In each Os(OF)3 cluster, Os2- is bonded in a distorted octahedral geometry to three O2- and three F1- atoms. All Os–O bond lengths are 1.73 Å. There are a spread of Os–F bond distances ranging from 1.99–2.01 Å. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded in a single-bond geometry to one Os2- atom. In the second O2- site, O2- is bonded in a single-bond geometry to one Os2- atom. In the third O2- site, O2- is bonded in a single-bond geometry to one Os2- atom. There are three inequivalent F1- sites. In the first F1- site, F1- is bonded in a single-bond geometry to one Os2- atom. In the second F1- site, F1- is bonded in a single-bond geometry to one Os2- atom. In the third F1- site, F1- is bonded in a single-bond geometry to one Os2- atom.

Authors:
Contributors:
Researcher:
Publication Date:
Other Number(s):
mp-738695
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; H12OsC4N(OF)3; C-F-H-N-O-Os
OSTI Identifier:
1287906
DOI:
10.17188/1287906

Citation Formats

Persson, Kristin, and Project, Materials. Materials Data on H12OsC4N(OF)3 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1287906.
Persson, Kristin, & Project, Materials. Materials Data on H12OsC4N(OF)3 by Materials Project. United States. doi:10.17188/1287906.
Persson, Kristin, and Project, Materials. 2020. "Materials Data on H12OsC4N(OF)3 by Materials Project". United States. doi:10.17188/1287906. https://www.osti.gov/servlets/purl/1287906. Pub date:Sat May 02 00:00:00 EDT 2020
@article{osti_1287906,
title = {Materials Data on H12OsC4N(OF)3 by Materials Project},
author = {Persson, Kristin and Project, Materials},
abstractNote = {Os(OF)3N(CH3)4 is Silicon tetrafluoride-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight tetramethylammonium molecules and eight Os(OF)3 clusters. In each Os(OF)3 cluster, Os2- is bonded in a distorted octahedral geometry to three O2- and three F1- atoms. All Os–O bond lengths are 1.73 Å. There are a spread of Os–F bond distances ranging from 1.99–2.01 Å. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded in a single-bond geometry to one Os2- atom. In the second O2- site, O2- is bonded in a single-bond geometry to one Os2- atom. In the third O2- site, O2- is bonded in a single-bond geometry to one Os2- atom. There are three inequivalent F1- sites. In the first F1- site, F1- is bonded in a single-bond geometry to one Os2- atom. In the second F1- site, F1- is bonded in a single-bond geometry to one Os2- atom. In the third F1- site, F1- is bonded in a single-bond geometry to one Os2- atom.},
doi = {10.17188/1287906},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {5}
}

Dataset:

Save / Share: