U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on Sb3H36(C3I2)4 by Materials Project
Abstract
((CH3)4Sb)3(I)8 crystallizes in the cubic I-43d space group. The structure is zero-dimensional and consists of thirty-two hydriodic acid molecules and twelve (CH3)4Sb clusters. In each (CH3)4Sb cluster, C+2.67- is bonded in a distorted trigonal non-coplanar geometry to one Sb+1.33+ and three H1+ atoms. The C–Sb bond length is 2.14 Å. There is one shorter (1.09 Å) and two longer (1.10 Å) C–H bond length. Sb+1.33+ is bonded in a tetrahedral geometry to four equivalent C+2.67- atoms. There are two inequivalent H1+ sites. In the first H1+ site, H1+ is bonded in a single-bond geometry to one C+2.67- atom. In the second H1+ site, H1+ is bonded in a single-bond geometry to one C+2.67- atom.
- Authors:
- Publication Date:
- Other Number(s):
- mp-733600
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Collaborations:
- MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE
- Keywords:
- crystal structure; Sb3H36(C3I2)4; C-H-I-Sb
- OSTI Identifier:
- 1287691
- DOI:
- https://doi.org/10.17188/1287691
Citation Formats
The Materials Project. Materials Data on Sb3H36(C3I2)4 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1287691.
The Materials Project. Materials Data on Sb3H36(C3I2)4 by Materials Project. United States. doi:https://doi.org/10.17188/1287691
The Materials Project. 2020.
"Materials Data on Sb3H36(C3I2)4 by Materials Project". United States. doi:https://doi.org/10.17188/1287691. https://www.osti.gov/servlets/purl/1287691. Pub date:Wed Apr 29 00:00:00 EDT 2020
@article{osti_1287691,
title = {Materials Data on Sb3H36(C3I2)4 by Materials Project},
author = {The Materials Project},
abstractNote = {((CH3)4Sb)3(I)8 crystallizes in the cubic I-43d space group. The structure is zero-dimensional and consists of thirty-two hydriodic acid molecules and twelve (CH3)4Sb clusters. In each (CH3)4Sb cluster, C+2.67- is bonded in a distorted trigonal non-coplanar geometry to one Sb+1.33+ and three H1+ atoms. The C–Sb bond length is 2.14 Å. There is one shorter (1.09 Å) and two longer (1.10 Å) C–H bond length. Sb+1.33+ is bonded in a tetrahedral geometry to four equivalent C+2.67- atoms. There are two inequivalent H1+ sites. In the first H1+ site, H1+ is bonded in a single-bond geometry to one C+2.67- atom. In the second H1+ site, H1+ is bonded in a single-bond geometry to one C+2.67- atom.},
doi = {10.17188/1287691},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {4}
}
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