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Title: Materials Data on Sb2S19F12 by Materials Project

Abstract

(SbF6)2(S)19 crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of seventy-six hydrogen sulfide molecules and eight SbF6 clusters. In each SbF6 cluster, Sb5+ is bonded in an octahedral geometry to six F1- atoms. There is three shorter (1.92 Å) and three longer (1.93 Å) Sb–F bond length. There are six inequivalent F1- sites. In the first F1- site, F1- is bonded in a single-bond geometry to one Sb5+ atom. In the second F1- site, F1- is bonded in a single-bond geometry to one Sb5+ atom. In the third F1- site, F1- is bonded in a single-bond geometry to one Sb5+ atom. In the fourth F1- site, F1- is bonded in a single-bond geometry to one Sb5+ atom. In the fifth F1- site, F1- is bonded in a single-bond geometry to one Sb5+ atom. In the sixth F1- site, F1- is bonded in a single-bond geometry to one Sb5+ atom.

Publication Date:
Other Number(s):
mp-723419
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; Sb2S19F12; F-S-Sb
OSTI Identifier:
1287603
DOI:
10.17188/1287603

Citation Formats

The Materials Project. Materials Data on Sb2S19F12 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1287603.
The Materials Project. Materials Data on Sb2S19F12 by Materials Project. United States. doi:10.17188/1287603.
The Materials Project. 2020. "Materials Data on Sb2S19F12 by Materials Project". United States. doi:10.17188/1287603. https://www.osti.gov/servlets/purl/1287603. Pub date:Wed Apr 29 00:00:00 EDT 2020
@article{osti_1287603,
title = {Materials Data on Sb2S19F12 by Materials Project},
author = {The Materials Project},
abstractNote = {(SbF6)2(S)19 crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of seventy-six hydrogen sulfide molecules and eight SbF6 clusters. In each SbF6 cluster, Sb5+ is bonded in an octahedral geometry to six F1- atoms. There is three shorter (1.92 Å) and three longer (1.93 Å) Sb–F bond length. There are six inequivalent F1- sites. In the first F1- site, F1- is bonded in a single-bond geometry to one Sb5+ atom. In the second F1- site, F1- is bonded in a single-bond geometry to one Sb5+ atom. In the third F1- site, F1- is bonded in a single-bond geometry to one Sb5+ atom. In the fourth F1- site, F1- is bonded in a single-bond geometry to one Sb5+ atom. In the fifth F1- site, F1- is bonded in a single-bond geometry to one Sb5+ atom. In the sixth F1- site, F1- is bonded in a single-bond geometry to one Sb5+ atom.},
doi = {10.17188/1287603},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {4}
}

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