skip to main content
DOE Data Explorer title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Materials Data on CsH24Rh(SO10)2 by Materials Project

Abstract

CsRhH24(SO10)2 crystallizes in the cubic Pa-3 space group. The structure is three-dimensional. Cs1+ is bonded in a distorted cuboctahedral geometry to six equivalent O2- atoms. All Cs–O bond lengths are 3.27 Å. Rh3+ is bonded in an octahedral geometry to six equivalent O2- atoms. All Rh–O bond lengths are 2.05 Å. There are four inequivalent H1+ sites. In the first H1+ site, H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.98 Å. In the second H1+ site, H1+ is bonded in a distorted linear geometry to two O2- atoms. There is one shorter (1.03 Å) and one longer (1.56 Å) H–O bond length. In the third H1+ site, H1+ is bonded in a single-bond geometry to two O2- atoms. There is one shorter (1.00 Å) and one longer (1.69 Å) H–O bond length. In the fourth H1+ site, H1+ is bonded in a single-bond geometry to two O2- atoms. There is one shorter (1.00 Å) and one longer (1.72 Å) H–O bond length. S6+ is bonded in a tetrahedral geometry to four O2- atoms. There is one shorter (1.49 Å) and three longer (1.50 Å) S–O bond length. There are four inequivalentmore » O2- sites. In the first O2- site, O2- is bonded in a distorted water-like geometry to one Rh3+ and two H1+ atoms. In the second O2- site, O2- is bonded in a single-bond geometry to one S6+ atom. In the third O2- site, O2- is bonded in a distorted trigonal non-coplanar geometry to one Cs1+ and three H1+ atoms. In the fourth O2- site, O2- is bonded in a 1-coordinate geometry to two H1+ and one S6+ atom.« less

Publication Date:
Other Number(s):
mp-707209
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; CsH24Rh(SO10)2; Cs-H-O-Rh-S
OSTI Identifier:
1286347
DOI:
10.17188/1286347

Citation Formats

The Materials Project. Materials Data on CsH24Rh(SO10)2 by Materials Project. United States: N. p., 2015. Web. doi:10.17188/1286347.
The Materials Project. Materials Data on CsH24Rh(SO10)2 by Materials Project. United States. doi:10.17188/1286347.
The Materials Project. 2015. "Materials Data on CsH24Rh(SO10)2 by Materials Project". United States. doi:10.17188/1286347. https://www.osti.gov/servlets/purl/1286347. Pub date:Mon Jan 05 00:00:00 EST 2015
@article{osti_1286347,
title = {Materials Data on CsH24Rh(SO10)2 by Materials Project},
author = {The Materials Project},
abstractNote = {CsRhH24(SO10)2 crystallizes in the cubic Pa-3 space group. The structure is three-dimensional. Cs1+ is bonded in a distorted cuboctahedral geometry to six equivalent O2- atoms. All Cs–O bond lengths are 3.27 Å. Rh3+ is bonded in an octahedral geometry to six equivalent O2- atoms. All Rh–O bond lengths are 2.05 Å. There are four inequivalent H1+ sites. In the first H1+ site, H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.98 Å. In the second H1+ site, H1+ is bonded in a distorted linear geometry to two O2- atoms. There is one shorter (1.03 Å) and one longer (1.56 Å) H–O bond length. In the third H1+ site, H1+ is bonded in a single-bond geometry to two O2- atoms. There is one shorter (1.00 Å) and one longer (1.69 Å) H–O bond length. In the fourth H1+ site, H1+ is bonded in a single-bond geometry to two O2- atoms. There is one shorter (1.00 Å) and one longer (1.72 Å) H–O bond length. S6+ is bonded in a tetrahedral geometry to four O2- atoms. There is one shorter (1.49 Å) and three longer (1.50 Å) S–O bond length. There are four inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted water-like geometry to one Rh3+ and two H1+ atoms. In the second O2- site, O2- is bonded in a single-bond geometry to one S6+ atom. In the third O2- site, O2- is bonded in a distorted trigonal non-coplanar geometry to one Cs1+ and three H1+ atoms. In the fourth O2- site, O2- is bonded in a 1-coordinate geometry to two H1+ and one S6+ atom.},
doi = {10.17188/1286347},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2015},
month = {1}
}

Dataset:

Save / Share: