U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on AgH12C4S5N by Materials Project
Abstract
AgS5N(CH3)4 crystallizes in the monoclinic Cc space group. The structure is one-dimensional and consists of four tetramethylammonium molecules and two AgS5 ribbons oriented in the (0, 0, 1) direction. In each AgS5 ribbon, Ag1+ is bonded to four S2- atoms to form corner-sharing AgS4 tetrahedra. There are a spread of Ag–S bond distances ranging from 2.57–2.74 Å. There are five inequivalent S2- sites. In the first S2- site, S2- is bonded in a distorted trigonal non-coplanar geometry to two equivalent Ag1+ and one S2- atom. The S–S bond length is 2.07 Å. In the second S2- site, S2- is bonded in a water-like geometry to one Ag1+ and one S2- atom. The S–S bond length is 2.06 Å. In the third S2- site, S2- is bonded in a water-like geometry to two S2- atoms. The S–S bond length is 2.06 Å. In the fourth S2- site, S2- is bonded in a water-like geometry to two S2- atoms. The S–S bond length is 2.08 Å. In the fifth S2- site, S2- is bonded in a trigonal non-coplanar geometry to one Ag1+ and two S2- atoms.
- Publication Date:
- Other Number(s):
- mp-698405
- DOE Contract Number:
- AC02-05CH11231
- Research Org.:
- LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- Collaborations:
- The Materials Project; MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE; Ag-C-H-N-S; AgH12C4S5N; crystal structure
- OSTI Identifier:
- 1285344
- DOI:
- https://doi.org/10.17188/1285344
Citation Formats
Materials Data on AgH12C4S5N by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1285344.
Materials Data on AgH12C4S5N by Materials Project. United States. doi:https://doi.org/10.17188/1285344
2020.
"Materials Data on AgH12C4S5N by Materials Project". United States. doi:https://doi.org/10.17188/1285344. https://www.osti.gov/servlets/purl/1285344. Pub date:Fri May 01 04:00:00 UTC 2020
@article{osti_1285344,
title = {Materials Data on AgH12C4S5N by Materials Project},
abstractNote = {AgS5N(CH3)4 crystallizes in the monoclinic Cc space group. The structure is one-dimensional and consists of four tetramethylammonium molecules and two AgS5 ribbons oriented in the (0, 0, 1) direction. In each AgS5 ribbon, Ag1+ is bonded to four S2- atoms to form corner-sharing AgS4 tetrahedra. There are a spread of Ag–S bond distances ranging from 2.57–2.74 Å. There are five inequivalent S2- sites. In the first S2- site, S2- is bonded in a distorted trigonal non-coplanar geometry to two equivalent Ag1+ and one S2- atom. The S–S bond length is 2.07 Å. In the second S2- site, S2- is bonded in a water-like geometry to one Ag1+ and one S2- atom. The S–S bond length is 2.06 Å. In the third S2- site, S2- is bonded in a water-like geometry to two S2- atoms. The S–S bond length is 2.06 Å. In the fourth S2- site, S2- is bonded in a water-like geometry to two S2- atoms. The S–S bond length is 2.08 Å. In the fifth S2- site, S2- is bonded in a trigonal non-coplanar geometry to one Ag1+ and two S2- atoms.},
doi = {10.17188/1285344},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {5}
}