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Title: Materials Data on Ag7NO8 by Materials Project

Abstract

Ag7NO8 crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. there are two inequivalent Ag+1.57+ sites. In the first Ag+1.57+ site, Ag+1.57+ is bonded in a body-centered cubic geometry to eight equivalent O2- atoms. All Ag–O bond lengths are 2.27 Å. In the second Ag+1.57+ site, Ag+1.57+ is bonded in a 5-coordinate geometry to one N5+ and four equivalent O2- atoms. The Ag–N bond length is 2.19 Å. All Ag–O bond lengths are 2.39 Å. N5+ is bonded to six equivalent Ag+1.57+ atoms to form NAg6 octahedra that share corners with twenty-four equivalent OAg4 tetrahedra. O2- is bonded to four Ag+1.57+ atoms to form distorted OAg4 tetrahedra that share corners with three equivalent NAg6 octahedra, a cornercorner with one OAg4 tetrahedra, edges with three equivalent OAg4 tetrahedra, and faces with three equivalent OAg4 tetrahedra. The corner-sharing octahedral tilt angles are 51°.

Publication Date:
Other Number(s):
mp-690667
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; Ag7NO8; Ag-N-O
OSTI Identifier:
1284556
DOI:
https://doi.org/10.17188/1284556

Citation Formats

The Materials Project. Materials Data on Ag7NO8 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1284556.
The Materials Project. Materials Data on Ag7NO8 by Materials Project. United States. doi:https://doi.org/10.17188/1284556
The Materials Project. 2020. "Materials Data on Ag7NO8 by Materials Project". United States. doi:https://doi.org/10.17188/1284556. https://www.osti.gov/servlets/purl/1284556. Pub date:Wed Jul 15 00:00:00 EDT 2020
@article{osti_1284556,
title = {Materials Data on Ag7NO8 by Materials Project},
author = {The Materials Project},
abstractNote = {Ag7NO8 crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. there are two inequivalent Ag+1.57+ sites. In the first Ag+1.57+ site, Ag+1.57+ is bonded in a body-centered cubic geometry to eight equivalent O2- atoms. All Ag–O bond lengths are 2.27 Å. In the second Ag+1.57+ site, Ag+1.57+ is bonded in a 5-coordinate geometry to one N5+ and four equivalent O2- atoms. The Ag–N bond length is 2.19 Å. All Ag–O bond lengths are 2.39 Å. N5+ is bonded to six equivalent Ag+1.57+ atoms to form NAg6 octahedra that share corners with twenty-four equivalent OAg4 tetrahedra. O2- is bonded to four Ag+1.57+ atoms to form distorted OAg4 tetrahedra that share corners with three equivalent NAg6 octahedra, a cornercorner with one OAg4 tetrahedra, edges with three equivalent OAg4 tetrahedra, and faces with three equivalent OAg4 tetrahedra. The corner-sharing octahedral tilt angles are 51°.},
doi = {10.17188/1284556},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}