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Title: Materials Data on MnSb2Pb5O11 by Materials Project

Abstract

Pb5Sb2MnO11 crystallizes in the orthorhombic Cmcm space group. The structure is three-dimensional. Mn2+ is bonded in a 7-coordinate geometry to seven O2- atoms. There are a spread of Mn–O bond distances ranging from 2.26–2.46 Å. There are three inequivalent Pb2+ sites. In the first Pb2+ site, Pb2+ is bonded in a distorted pentagonal planar geometry to five O2- atoms. There are one shorter (2.34 Å) and four longer (2.49 Å) Pb–O bond lengths. In the second Pb2+ site, Pb2+ is bonded in a 6-coordinate geometry to six O2- atoms. There are a spread of Pb–O bond distances ranging from 2.42–2.92 Å. In the third Pb2+ site, Pb2+ is bonded in a 7-coordinate geometry to five O2- atoms. There are a spread of Pb–O bond distances ranging from 2.41–2.55 Å. Sb5+ is bonded to six O2- atoms to form edge-sharing SbO6 octahedra. There are a spread of Sb–O bond distances ranging from 1.98–2.10 Å. There are four inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted rectangular see-saw-like geometry to one Mn2+, two Pb2+, and one Sb5+ atom. In the second O2- site, O2- is bonded in a distorted rectangular see-saw-like geometry to three Pb2+ andmore » one Sb5+ atom. In the third O2- site, O2- is bonded in a 3-coordinate geometry to one Mn2+, one Pb2+, and two equivalent Sb5+ atoms. In the fourth O2- site, O2- is bonded in an octahedral geometry to one Mn2+ and five Pb2+ atoms.« less

Authors:
Contributors:
Researcher:
Publication Date:
Other Number(s):
mp-687227
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; MnSb2Pb5O11; Mn-O-Pb-Sb
OSTI Identifier:
1284424
DOI:
10.17188/1284424

Citation Formats

Persson, Kristin, and Project, Materials. Materials Data on MnSb2Pb5O11 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1284424.
Persson, Kristin, & Project, Materials. Materials Data on MnSb2Pb5O11 by Materials Project. United States. doi:10.17188/1284424.
Persson, Kristin, and Project, Materials. 2020. "Materials Data on MnSb2Pb5O11 by Materials Project". United States. doi:10.17188/1284424. https://www.osti.gov/servlets/purl/1284424. Pub date:Sat May 02 00:00:00 EDT 2020
@article{osti_1284424,
title = {Materials Data on MnSb2Pb5O11 by Materials Project},
author = {Persson, Kristin and Project, Materials},
abstractNote = {Pb5Sb2MnO11 crystallizes in the orthorhombic Cmcm space group. The structure is three-dimensional. Mn2+ is bonded in a 7-coordinate geometry to seven O2- atoms. There are a spread of Mn–O bond distances ranging from 2.26–2.46 Å. There are three inequivalent Pb2+ sites. In the first Pb2+ site, Pb2+ is bonded in a distorted pentagonal planar geometry to five O2- atoms. There are one shorter (2.34 Å) and four longer (2.49 Å) Pb–O bond lengths. In the second Pb2+ site, Pb2+ is bonded in a 6-coordinate geometry to six O2- atoms. There are a spread of Pb–O bond distances ranging from 2.42–2.92 Å. In the third Pb2+ site, Pb2+ is bonded in a 7-coordinate geometry to five O2- atoms. There are a spread of Pb–O bond distances ranging from 2.41–2.55 Å. Sb5+ is bonded to six O2- atoms to form edge-sharing SbO6 octahedra. There are a spread of Sb–O bond distances ranging from 1.98–2.10 Å. There are four inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted rectangular see-saw-like geometry to one Mn2+, two Pb2+, and one Sb5+ atom. In the second O2- site, O2- is bonded in a distorted rectangular see-saw-like geometry to three Pb2+ and one Sb5+ atom. In the third O2- site, O2- is bonded in a 3-coordinate geometry to one Mn2+, one Pb2+, and two equivalent Sb5+ atoms. In the fourth O2- site, O2- is bonded in an octahedral geometry to one Mn2+ and five Pb2+ atoms.},
doi = {10.17188/1284424},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {5}
}

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