U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on VCo3 by Materials Project
Abstract
Co3V crystallizes in the hexagonal P6/mmm space group. The structure is two-dimensional and consists of one Co3V sheet oriented in the (0, 0, 1) direction. there are two inequivalent V sites. In the first V site, V is bonded to one V and six Co atoms to form distorted corner-sharing VVCo6 hexagonal pyramids. The V–V bond length is 2.53 Å. There are three shorter (2.28 Å) and three longer (2.40 Å) V–Co bond lengths. In the second V site, V is bonded in a distorted hexagonal planar geometry to six equivalent Co atoms. All V–Co bond lengths are 2.43 Å. There are two inequivalent Co sites. In the first Co site, Co is bonded in a 2-coordinate geometry to two equivalent V and four equivalent Co atoms. All Co–Co bond lengths are 2.44 Å. In the second Co site, Co is bonded in a 7-coordinate geometry to two V and five Co atoms. There are one shorter (2.27 Å) and two longer (2.31 Å) Co–Co bond lengths.
- Authors:
- Publication Date:
- Other Number(s):
- mp-680599
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Collaborations:
- MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE
- Keywords:
- crystal structure; VCo3; Co-V
- OSTI Identifier:
- 1283684
- DOI:
- https://doi.org/10.17188/1283684
Citation Formats
The Materials Project. Materials Data on VCo3 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1283684.
The Materials Project. Materials Data on VCo3 by Materials Project. United States. doi:https://doi.org/10.17188/1283684
The Materials Project. 2020.
"Materials Data on VCo3 by Materials Project". United States. doi:https://doi.org/10.17188/1283684. https://www.osti.gov/servlets/purl/1283684. Pub date:Fri May 01 00:00:00 EDT 2020
@article{osti_1283684,
title = {Materials Data on VCo3 by Materials Project},
author = {The Materials Project},
abstractNote = {Co3V crystallizes in the hexagonal P6/mmm space group. The structure is two-dimensional and consists of one Co3V sheet oriented in the (0, 0, 1) direction. there are two inequivalent V sites. In the first V site, V is bonded to one V and six Co atoms to form distorted corner-sharing VVCo6 hexagonal pyramids. The V–V bond length is 2.53 Å. There are three shorter (2.28 Å) and three longer (2.40 Å) V–Co bond lengths. In the second V site, V is bonded in a distorted hexagonal planar geometry to six equivalent Co atoms. All V–Co bond lengths are 2.43 Å. There are two inequivalent Co sites. In the first Co site, Co is bonded in a 2-coordinate geometry to two equivalent V and four equivalent Co atoms. All Co–Co bond lengths are 2.44 Å. In the second Co site, Co is bonded in a 7-coordinate geometry to two V and five Co atoms. There are one shorter (2.27 Å) and two longer (2.31 Å) Co–Co bond lengths.},
doi = {10.17188/1283684},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {5}
}