U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on KCN by Materials Project
Abstract
KCN crystallizes in the triclinic P1 space group. The structure is three-dimensional. there are four inequivalent K1+ sites. In the first K1+ site, K1+ is bonded in a 5-coordinate geometry to five N3- atoms. There are a spread of K–N bond distances ranging from 2.85–3.02 Å. In the second K1+ site, K1+ is bonded in a distorted single-bond geometry to one N3- atom. The K–N bond length is 2.81 Å. In the third K1+ site, K1+ is bonded in a 1-coordinate geometry to six N3- atoms. There are a spread of K–N bond distances ranging from 2.82–3.30 Å. In the fourth K1+ site, K1+ is bonded in a 2-coordinate geometry to two N3- atoms. There are one shorter (2.81 Å) and one longer (2.96 Å) K–N bond lengths. There are four inequivalent C2+ sites. In the first C2+ site, C2+ is bonded in a single-bond geometry to one N3- atom. The C–N bond length is 1.36 Å. In the second C2+ site, C2+ is bonded in a single-bond geometry to one N3- atom. The C–N bond length is 1.41 Å. In the third C2+ site, C2+ is bonded in a single-bond geometry to one N3- atom. The C–N bond lengthmore »
- Publication Date:
- Other Number(s):
- mp-676693
- DOE Contract Number:
- AC02-05CH11231
- Research Org.:
- LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- Collaborations:
- The Materials Project; MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE; C-K-N; KCN; crystal structure
- OSTI Identifier:
- 1283140
- DOI:
- https://doi.org/10.17188/1283140
Citation Formats
Materials Data on KCN by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1283140.
Materials Data on KCN by Materials Project. United States. doi:https://doi.org/10.17188/1283140
2020.
"Materials Data on KCN by Materials Project". United States. doi:https://doi.org/10.17188/1283140. https://www.osti.gov/servlets/purl/1283140. Pub date:Mon Jul 20 00:00:00 EDT 2020
@article{osti_1283140,
title = {Materials Data on KCN by Materials Project},
abstractNote = {KCN crystallizes in the triclinic P1 space group. The structure is three-dimensional. there are four inequivalent K1+ sites. In the first K1+ site, K1+ is bonded in a 5-coordinate geometry to five N3- atoms. There are a spread of K–N bond distances ranging from 2.85–3.02 Å. In the second K1+ site, K1+ is bonded in a distorted single-bond geometry to one N3- atom. The K–N bond length is 2.81 Å. In the third K1+ site, K1+ is bonded in a 1-coordinate geometry to six N3- atoms. There are a spread of K–N bond distances ranging from 2.82–3.30 Å. In the fourth K1+ site, K1+ is bonded in a 2-coordinate geometry to two N3- atoms. There are one shorter (2.81 Å) and one longer (2.96 Å) K–N bond lengths. There are four inequivalent C2+ sites. In the first C2+ site, C2+ is bonded in a single-bond geometry to one N3- atom. The C–N bond length is 1.36 Å. In the second C2+ site, C2+ is bonded in a single-bond geometry to one N3- atom. The C–N bond length is 1.41 Å. In the third C2+ site, C2+ is bonded in a single-bond geometry to one N3- atom. The C–N bond length is 1.42 Å. In the fourth C2+ site, C2+ is bonded in a single-bond geometry to one N3- atom. The C–N bond length is 1.37 Å. There are four inequivalent N3- sites. In the first N3- site, N3- is bonded in a distorted single-bond geometry to three K1+ and one C2+ atom. In the second N3- site, N3- is bonded in a 1-coordinate geometry to four K1+ and one C2+ atom. In the third N3- site, N3- is bonded in a 1-coordinate geometry to four K1+ and one C2+ atom. In the fourth N3- site, N3- is bonded in a distorted single-bond geometry to three K1+ and one C2+ atom.},
doi = {10.17188/1283140},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}