U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on Ce5AgS8 by Materials Project
Abstract
Ce5AgS8 crystallizes in the tetragonal I-4 space group. The structure is three-dimensional. there are two inequivalent Ce3+ sites. In the first Ce3+ site, Ce3+ is bonded in a 8-coordinate geometry to eight S2- atoms. There are a spread of Ce–S bond distances ranging from 2.84–3.13 Å. In the second Ce3+ site, Ce3+ is bonded in a 8-coordinate geometry to eight S2- atoms. There are four shorter (2.85 Å) and four longer (3.02 Å) Ce–S bond lengths. Ag1+ is bonded in a distorted hexagonal bipyramidal geometry to eight S2- atoms. There are four shorter (2.85 Å) and four longer (3.19 Å) Ag–S bond lengths. There are two inequivalent S2- sites. In the first S2- site, S2- is bonded in a 6-coordinate geometry to five Ce3+ and one Ag1+ atom. In the second S2- site, S2- is bonded in a 6-coordinate geometry to five Ce3+ and one Ag1+ atom.
- Publication Date:
- Other Number(s):
- mp-675643
- DOE Contract Number:
- AC02-05CH11231
- Research Org.:
- LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- Collaborations:
- The Materials Project; MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE; Ag-Ce-S; Ce5AgS8; crystal structure
- OSTI Identifier:
- 1282784
- DOI:
- https://doi.org/10.17188/1282784
Citation Formats
Materials Data on Ce5AgS8 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1282784.
Materials Data on Ce5AgS8 by Materials Project. United States. doi:https://doi.org/10.17188/1282784
2020.
"Materials Data on Ce5AgS8 by Materials Project". United States. doi:https://doi.org/10.17188/1282784. https://www.osti.gov/servlets/purl/1282784. Pub date:Thu Apr 30 00:00:00 EDT 2020
@article{osti_1282784,
title = {Materials Data on Ce5AgS8 by Materials Project},
abstractNote = {Ce5AgS8 crystallizes in the tetragonal I-4 space group. The structure is three-dimensional. there are two inequivalent Ce3+ sites. In the first Ce3+ site, Ce3+ is bonded in a 8-coordinate geometry to eight S2- atoms. There are a spread of Ce–S bond distances ranging from 2.84–3.13 Å. In the second Ce3+ site, Ce3+ is bonded in a 8-coordinate geometry to eight S2- atoms. There are four shorter (2.85 Å) and four longer (3.02 Å) Ce–S bond lengths. Ag1+ is bonded in a distorted hexagonal bipyramidal geometry to eight S2- atoms. There are four shorter (2.85 Å) and four longer (3.19 Å) Ag–S bond lengths. There are two inequivalent S2- sites. In the first S2- site, S2- is bonded in a 6-coordinate geometry to five Ce3+ and one Ag1+ atom. In the second S2- site, S2- is bonded in a 6-coordinate geometry to five Ce3+ and one Ag1+ atom.},
doi = {10.17188/1282784},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {4}
}