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Title: Materials Data on Ce5AgS8 by Materials Project

Abstract

Ce5AgS8 crystallizes in the tetragonal I-4 space group. The structure is three-dimensional. there are two inequivalent Ce3+ sites. In the first Ce3+ site, Ce3+ is bonded in a 8-coordinate geometry to eight S2- atoms. There are a spread of Ce–S bond distances ranging from 2.84–3.13 Å. In the second Ce3+ site, Ce3+ is bonded in a 8-coordinate geometry to eight S2- atoms. There are four shorter (2.85 Å) and four longer (3.02 Å) Ce–S bond lengths. Ag1+ is bonded in a distorted hexagonal bipyramidal geometry to eight S2- atoms. There are four shorter (2.85 Å) and four longer (3.19 Å) Ag–S bond lengths. There are two inequivalent S2- sites. In the first S2- site, S2- is bonded in a 6-coordinate geometry to five Ce3+ and one Ag1+ atom. In the second S2- site, S2- is bonded in a 6-coordinate geometry to five Ce3+ and one Ag1+ atom.

Authors:
Publication Date:
Other Number(s):
mp-675643
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Collaborations:
MIT; UC Berkeley; Duke; U Louvain
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; Ce5AgS8; Ag-Ce-S
OSTI Identifier:
1282784
DOI:
https://doi.org/10.17188/1282784

Citation Formats

The Materials Project. Materials Data on Ce5AgS8 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1282784.
The Materials Project. Materials Data on Ce5AgS8 by Materials Project. United States. doi:https://doi.org/10.17188/1282784
The Materials Project. 2020. "Materials Data on Ce5AgS8 by Materials Project". United States. doi:https://doi.org/10.17188/1282784. https://www.osti.gov/servlets/purl/1282784. Pub date:Thu Apr 30 00:00:00 EDT 2020
@article{osti_1282784,
title = {Materials Data on Ce5AgS8 by Materials Project},
author = {The Materials Project},
abstractNote = {Ce5AgS8 crystallizes in the tetragonal I-4 space group. The structure is three-dimensional. there are two inequivalent Ce3+ sites. In the first Ce3+ site, Ce3+ is bonded in a 8-coordinate geometry to eight S2- atoms. There are a spread of Ce–S bond distances ranging from 2.84–3.13 Å. In the second Ce3+ site, Ce3+ is bonded in a 8-coordinate geometry to eight S2- atoms. There are four shorter (2.85 Å) and four longer (3.02 Å) Ce–S bond lengths. Ag1+ is bonded in a distorted hexagonal bipyramidal geometry to eight S2- atoms. There are four shorter (2.85 Å) and four longer (3.19 Å) Ag–S bond lengths. There are two inequivalent S2- sites. In the first S2- site, S2- is bonded in a 6-coordinate geometry to five Ce3+ and one Ag1+ atom. In the second S2- site, S2- is bonded in a 6-coordinate geometry to five Ce3+ and one Ag1+ atom.},
doi = {10.17188/1282784},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {4}
}