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Title: Materials Data on SbRhO4 by Materials Project

Abstract

RhSbO4 is Hydrophilite-derived structured and crystallizes in the orthorhombic Cmmm space group. The structure is three-dimensional. Rh3+ is bonded to six O2- atoms to form RhO6 octahedra that share corners with eight equivalent SbO6 octahedra and edges with two equivalent RhO6 octahedra. The corner-sharing octahedral tilt angles are 52°. All Rh–O bond lengths are 2.05 Å. Sb5+ is bonded to six O2- atoms to form SbO6 octahedra that share corners with eight equivalent RhO6 octahedra and edges with two equivalent SbO6 octahedra. The corner-sharing octahedral tilt angles are 52°. There are two shorter (2.01 Å) and four longer (2.05 Å) Sb–O bond lengths. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded in a trigonal planar geometry to two equivalent Rh3+ and one Sb5+ atom. In the second O2- site, O2- is bonded in a trigonal planar geometry to one Rh3+ and two equivalent Sb5+ atoms.

Publication Date:
Other Number(s):
mp-675025
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; SbRhO4; O-Rh-Sb
OSTI Identifier:
1282557
DOI:
https://doi.org/10.17188/1282557

Citation Formats

The Materials Project. Materials Data on SbRhO4 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1282557.
The Materials Project. Materials Data on SbRhO4 by Materials Project. United States. doi:https://doi.org/10.17188/1282557
The Materials Project. 2020. "Materials Data on SbRhO4 by Materials Project". United States. doi:https://doi.org/10.17188/1282557. https://www.osti.gov/servlets/purl/1282557. Pub date:Mon Jul 20 00:00:00 EDT 2020
@article{osti_1282557,
title = {Materials Data on SbRhO4 by Materials Project},
author = {The Materials Project},
abstractNote = {RhSbO4 is Hydrophilite-derived structured and crystallizes in the orthorhombic Cmmm space group. The structure is three-dimensional. Rh3+ is bonded to six O2- atoms to form RhO6 octahedra that share corners with eight equivalent SbO6 octahedra and edges with two equivalent RhO6 octahedra. The corner-sharing octahedral tilt angles are 52°. All Rh–O bond lengths are 2.05 Å. Sb5+ is bonded to six O2- atoms to form SbO6 octahedra that share corners with eight equivalent RhO6 octahedra and edges with two equivalent SbO6 octahedra. The corner-sharing octahedral tilt angles are 52°. There are two shorter (2.01 Å) and four longer (2.05 Å) Sb–O bond lengths. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded in a trigonal planar geometry to two equivalent Rh3+ and one Sb5+ atom. In the second O2- site, O2- is bonded in a trigonal planar geometry to one Rh3+ and two equivalent Sb5+ atoms.},
doi = {10.17188/1282557},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}