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Title: Materials Data on Hg2SbF6 by Materials Project

Abstract

Hg2SbF6 crystallizes in the monoclinic C2/c space group. The structure is three-dimensional. there are two inequivalent Hg+1.50+ sites. In the first Hg+1.50+ site, Hg+1.50+ is bonded in a distorted rectangular see-saw-like geometry to four F1- atoms. There are two shorter (2.89 Å) and two longer (2.95 Å) Hg–F bond lengths. In the second Hg+1.50+ site, Hg+1.50+ is bonded in a 4-coordinate geometry to four F1- atoms. There are two shorter (2.86 Å) and two longer (2.94 Å) Hg–F bond lengths. Sb3+ is bonded in an octahedral geometry to six F1- atoms. All Sb–F bond lengths are 1.92 Å. There are six inequivalent F1- sites. In the first F1- site, F1- is bonded in a distorted single-bond geometry to two equivalent Hg+1.50+ and one Sb3+ atom. In the second F1- site, F1- is bonded in a distorted single-bond geometry to two Hg+1.50+ and one Sb3+ atom. In the third F1- site, F1- is bonded in a single-bond geometry to one Sb3+ atom. In the fourth F1- site, F1- is bonded in a distorted single-bond geometry to two equivalent Hg+1.50+ and one Sb3+ atom. In the fifth F1- site, F1- is bonded in a distorted single-bond geometry to two equivalent Hg+1.50+ andmore » one Sb3+ atom. Both F–Hg bond lengths are 2.94 Å. The F–Sb bond length is 1.92 Å. In the sixth F1- site, F1- is bonded in a distorted single-bond geometry to two equivalent Hg+1.50+ and one Sb3+ atom. Both F–Hg bond lengths are 2.89 Å. The F–Sb bond length is 1.92 Å.« less

Publication Date:
Other Number(s):
mp-674503
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; Hg2SbF6; F-Hg-Sb
OSTI Identifier:
1282507
DOI:
10.17188/1282507

Citation Formats

The Materials Project. Materials Data on Hg2SbF6 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1282507.
The Materials Project. Materials Data on Hg2SbF6 by Materials Project. United States. doi:10.17188/1282507.
The Materials Project. 2020. "Materials Data on Hg2SbF6 by Materials Project". United States. doi:10.17188/1282507. https://www.osti.gov/servlets/purl/1282507. Pub date:Sun May 03 00:00:00 EDT 2020
@article{osti_1282507,
title = {Materials Data on Hg2SbF6 by Materials Project},
author = {The Materials Project},
abstractNote = {Hg2SbF6 crystallizes in the monoclinic C2/c space group. The structure is three-dimensional. there are two inequivalent Hg+1.50+ sites. In the first Hg+1.50+ site, Hg+1.50+ is bonded in a distorted rectangular see-saw-like geometry to four F1- atoms. There are two shorter (2.89 Å) and two longer (2.95 Å) Hg–F bond lengths. In the second Hg+1.50+ site, Hg+1.50+ is bonded in a 4-coordinate geometry to four F1- atoms. There are two shorter (2.86 Å) and two longer (2.94 Å) Hg–F bond lengths. Sb3+ is bonded in an octahedral geometry to six F1- atoms. All Sb–F bond lengths are 1.92 Å. There are six inequivalent F1- sites. In the first F1- site, F1- is bonded in a distorted single-bond geometry to two equivalent Hg+1.50+ and one Sb3+ atom. In the second F1- site, F1- is bonded in a distorted single-bond geometry to two Hg+1.50+ and one Sb3+ atom. In the third F1- site, F1- is bonded in a single-bond geometry to one Sb3+ atom. In the fourth F1- site, F1- is bonded in a distorted single-bond geometry to two equivalent Hg+1.50+ and one Sb3+ atom. In the fifth F1- site, F1- is bonded in a distorted single-bond geometry to two equivalent Hg+1.50+ and one Sb3+ atom. Both F–Hg bond lengths are 2.94 Å. The F–Sb bond length is 1.92 Å. In the sixth F1- site, F1- is bonded in a distorted single-bond geometry to two equivalent Hg+1.50+ and one Sb3+ atom. Both F–Hg bond lengths are 2.89 Å. The F–Sb bond length is 1.92 Å.},
doi = {10.17188/1282507},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {5}
}

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