skip to main content
DOE Data Explorer title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Materials Data on Sn(PO3)3 by Materials Project

Abstract

Sn(PO3)3 crystallizes in the hexagonal P-6c2 space group. The structure is three-dimensional. Sn3+ is bonded to six equivalent O2- atoms to form SnO6 octahedra that share corners with six equivalent PO4 tetrahedra. All Sn–O bond lengths are 2.24 Å. P5+ is bonded to four O2- atoms to form PO4 tetrahedra that share corners with two equivalent SnO6 octahedra and corners with two equivalent PO4 tetrahedra. The corner-sharing octahedral tilt angles are 42°. There is two shorter (1.51 Å) and two longer (1.61 Å) P–O bond length. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted bent 150 degrees geometry to two equivalent P5+ atoms. In the second O2- site, O2- is bonded in a distorted bent 150 degrees geometry to one Sn3+ and one P5+ atom.

Publication Date:
Other Number(s):
mp-673129
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; Sn(PO3)3; O-P-Sn
OSTI Identifier:
1282341
DOI:
10.17188/1282341

Citation Formats

The Materials Project. Materials Data on Sn(PO3)3 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1282341.
The Materials Project. Materials Data on Sn(PO3)3 by Materials Project. United States. doi:10.17188/1282341.
The Materials Project. 2020. "Materials Data on Sn(PO3)3 by Materials Project". United States. doi:10.17188/1282341. https://www.osti.gov/servlets/purl/1282341. Pub date:Fri May 01 00:00:00 EDT 2020
@article{osti_1282341,
title = {Materials Data on Sn(PO3)3 by Materials Project},
author = {The Materials Project},
abstractNote = {Sn(PO3)3 crystallizes in the hexagonal P-6c2 space group. The structure is three-dimensional. Sn3+ is bonded to six equivalent O2- atoms to form SnO6 octahedra that share corners with six equivalent PO4 tetrahedra. All Sn–O bond lengths are 2.24 Å. P5+ is bonded to four O2- atoms to form PO4 tetrahedra that share corners with two equivalent SnO6 octahedra and corners with two equivalent PO4 tetrahedra. The corner-sharing octahedral tilt angles are 42°. There is two shorter (1.51 Å) and two longer (1.61 Å) P–O bond length. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted bent 150 degrees geometry to two equivalent P5+ atoms. In the second O2- site, O2- is bonded in a distorted bent 150 degrees geometry to one Sn3+ and one P5+ atom.},
doi = {10.17188/1282341},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {5}
}

Dataset:

Save / Share: