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Title: Materials Data on Sn2P3O10 by Materials Project

Abstract

Sn2P3O10 crystallizes in the monoclinic C2/c space group. The structure is two-dimensional and consists of two Sn2P3O10 sheets oriented in the (0, 0, 1) direction. Sn+2.50+ is bonded in a distorted rectangular see-saw-like geometry to four O2- atoms. There are a spread of Sn–O bond distances ranging from 2.16–2.37 Å. There are two inequivalent P5+ sites. In the first P5+ site, P5+ is bonded to four O2- atoms to form corner-sharing PO4 tetrahedra. There is two shorter (1.51 Å) and two longer (1.60 Å) P–O bond length. In the second P5+ site, P5+ is bonded to four O2- atoms to form corner-sharing PO4 tetrahedra. There are a spread of P–O bond distances ranging from 1.53–1.65 Å. There are five inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted single-bond geometry to one Sn+2.50+ and one P5+ atom. In the second O2- site, O2- is bonded in a 2-coordinate geometry to one Sn+2.50+ and one P5+ atom. In the third O2- site, O2- is bonded in a bent 120 degrees geometry to two P5+ atoms. In the fourth O2- site, O2- is bonded in a 2-coordinate geometry to one Sn+2.50+ and one P5+ atom. In themore » fifth O2- site, O2- is bonded in a distorted L-shaped geometry to one Sn+2.50+ and one P5+ atom.« less

Publication Date:
Other Number(s):
mp-673117
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; Sn2P3O10; O-P-Sn
OSTI Identifier:
1282336
DOI:
10.17188/1282336

Citation Formats

The Materials Project. Materials Data on Sn2P3O10 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1282336.
The Materials Project. Materials Data on Sn2P3O10 by Materials Project. United States. doi:10.17188/1282336.
The Materials Project. 2020. "Materials Data on Sn2P3O10 by Materials Project". United States. doi:10.17188/1282336. https://www.osti.gov/servlets/purl/1282336. Pub date:Fri May 01 00:00:00 EDT 2020
@article{osti_1282336,
title = {Materials Data on Sn2P3O10 by Materials Project},
author = {The Materials Project},
abstractNote = {Sn2P3O10 crystallizes in the monoclinic C2/c space group. The structure is two-dimensional and consists of two Sn2P3O10 sheets oriented in the (0, 0, 1) direction. Sn+2.50+ is bonded in a distorted rectangular see-saw-like geometry to four O2- atoms. There are a spread of Sn–O bond distances ranging from 2.16–2.37 Å. There are two inequivalent P5+ sites. In the first P5+ site, P5+ is bonded to four O2- atoms to form corner-sharing PO4 tetrahedra. There is two shorter (1.51 Å) and two longer (1.60 Å) P–O bond length. In the second P5+ site, P5+ is bonded to four O2- atoms to form corner-sharing PO4 tetrahedra. There are a spread of P–O bond distances ranging from 1.53–1.65 Å. There are five inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted single-bond geometry to one Sn+2.50+ and one P5+ atom. In the second O2- site, O2- is bonded in a 2-coordinate geometry to one Sn+2.50+ and one P5+ atom. In the third O2- site, O2- is bonded in a bent 120 degrees geometry to two P5+ atoms. In the fourth O2- site, O2- is bonded in a 2-coordinate geometry to one Sn+2.50+ and one P5+ atom. In the fifth O2- site, O2- is bonded in a distorted L-shaped geometry to one Sn+2.50+ and one P5+ atom.},
doi = {10.17188/1282336},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {5}
}

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