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Title: Materials Data on EuBi2IO4 by Materials Project

Abstract

EuBi2O4I is alpha bismuth trifluoride-derived structured and crystallizes in the triclinic P-1 space group. The structure is three-dimensional. Eu3+ is bonded in a body-centered cubic geometry to eight O2- atoms. There are four shorter (2.45 Å) and four longer (2.46 Å) Eu–O bond lengths. Bi3+ is bonded in a 4-coordinate geometry to four O2- and four equivalent I1- atoms. There are a spread of Bi–O bond distances ranging from 2.26–2.28 Å. There are a spread of Bi–I bond distances ranging from 3.66–3.69 Å. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded to two equivalent Eu3+ and two equivalent Bi3+ atoms to form a mixture of edge and corner-sharing OEu2Bi2 tetrahedra. In the second O2- site, O2- is bonded to two equivalent Eu3+ and two equivalent Bi3+ atoms to form a mixture of edge and corner-sharing OEu2Bi2 tetrahedra. I1- is bonded in a distorted body-centered cubic geometry to eight equivalent Bi3+ atoms.

Publication Date:
Other Number(s):
mp-669573
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; EuBi2IO4; Bi-Eu-I-O
OSTI Identifier:
1281712
DOI:
10.17188/1281712

Citation Formats

The Materials Project. Materials Data on EuBi2IO4 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1281712.
The Materials Project. Materials Data on EuBi2IO4 by Materials Project. United States. doi:10.17188/1281712.
The Materials Project. 2020. "Materials Data on EuBi2IO4 by Materials Project". United States. doi:10.17188/1281712. https://www.osti.gov/servlets/purl/1281712. Pub date:Mon Aug 03 00:00:00 EDT 2020
@article{osti_1281712,
title = {Materials Data on EuBi2IO4 by Materials Project},
author = {The Materials Project},
abstractNote = {EuBi2O4I is alpha bismuth trifluoride-derived structured and crystallizes in the triclinic P-1 space group. The structure is three-dimensional. Eu3+ is bonded in a body-centered cubic geometry to eight O2- atoms. There are four shorter (2.45 Å) and four longer (2.46 Å) Eu–O bond lengths. Bi3+ is bonded in a 4-coordinate geometry to four O2- and four equivalent I1- atoms. There are a spread of Bi–O bond distances ranging from 2.26–2.28 Å. There are a spread of Bi–I bond distances ranging from 3.66–3.69 Å. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded to two equivalent Eu3+ and two equivalent Bi3+ atoms to form a mixture of edge and corner-sharing OEu2Bi2 tetrahedra. In the second O2- site, O2- is bonded to two equivalent Eu3+ and two equivalent Bi3+ atoms to form a mixture of edge and corner-sharing OEu2Bi2 tetrahedra. I1- is bonded in a distorted body-centered cubic geometry to eight equivalent Bi3+ atoms.},
doi = {10.17188/1281712},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {8}
}

Dataset:

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