skip to main content
DOE Data Explorer title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Materials Data on Bi12PbO20 by Materials Project

Abstract

PbBi12O20 crystallizes in the cubic I23 space group. The structure is three-dimensional. Pb4+ is bonded to four equivalent O2- atoms to form PbO4 tetrahedra that share corners with twelve equivalent BiO5 square pyramids. All Pb–O bond lengths are 2.11 Å. Bi3+ is bonded to five O2- atoms to form distorted BiO5 square pyramids that share corners with eight equivalent BiO5 square pyramids, a cornercorner with one PbO4 tetrahedra, and an edgeedge with one BiO5 square pyramid. There are a spread of Bi–O bond distances ranging from 2.11–2.60 Å. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded in a trigonal planar geometry to three equivalent Bi3+ atoms. In the second O2- site, O2- is bonded in a distorted trigonal non-coplanar geometry to three equivalent Bi3+ atoms. In the third O2- site, O2- is bonded to one Pb4+ and three equivalent Bi3+ atoms to form corner-sharing OBi3Pb tetrahedra.

Publication Date:
Other Number(s):
mp-667342
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; Bi12PbO20; Bi-O-Pb
OSTI Identifier:
1281507
DOI:
10.17188/1281507

Citation Formats

The Materials Project. Materials Data on Bi12PbO20 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1281507.
The Materials Project. Materials Data on Bi12PbO20 by Materials Project. United States. doi:10.17188/1281507.
The Materials Project. 2020. "Materials Data on Bi12PbO20 by Materials Project". United States. doi:10.17188/1281507. https://www.osti.gov/servlets/purl/1281507. Pub date:Wed Jul 22 00:00:00 EDT 2020
@article{osti_1281507,
title = {Materials Data on Bi12PbO20 by Materials Project},
author = {The Materials Project},
abstractNote = {PbBi12O20 crystallizes in the cubic I23 space group. The structure is three-dimensional. Pb4+ is bonded to four equivalent O2- atoms to form PbO4 tetrahedra that share corners with twelve equivalent BiO5 square pyramids. All Pb–O bond lengths are 2.11 Å. Bi3+ is bonded to five O2- atoms to form distorted BiO5 square pyramids that share corners with eight equivalent BiO5 square pyramids, a cornercorner with one PbO4 tetrahedra, and an edgeedge with one BiO5 square pyramid. There are a spread of Bi–O bond distances ranging from 2.11–2.60 Å. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded in a trigonal planar geometry to three equivalent Bi3+ atoms. In the second O2- site, O2- is bonded in a distorted trigonal non-coplanar geometry to three equivalent Bi3+ atoms. In the third O2- site, O2- is bonded to one Pb4+ and three equivalent Bi3+ atoms to form corner-sharing OBi3Pb tetrahedra.},
doi = {10.17188/1281507},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}

Dataset:

Save / Share: