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Title: Materials Data on KSO2F by Materials Project

Abstract

KSO2F crystallizes in the monoclinic P2_1/m space group. The structure is three-dimensional. K1+ is bonded in a 9-coordinate geometry to six equivalent O2- and three equivalent F1- atoms. There are four shorter (2.90 Å) and two longer (3.00 Å) K–O bond lengths. There are one shorter (2.85 Å) and two longer (3.18 Å) K–F bond lengths. S4+ is bonded in a trigonal non-coplanar geometry to two equivalent O2- and one F1- atom. Both S–O bond lengths are 1.48 Å. The S–F bond length is 1.83 Å. O2- is bonded in a distorted single-bond geometry to three equivalent K1+ and one S4+ atom. F1- is bonded in a 2-coordinate geometry to three equivalent K1+ and one S4+ atom.

Authors:
Publication Date:
Other Number(s):
mp-6560
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Collaborations:
MIT; UC Berkeley; Duke; U Louvain
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; KSO2F; F-K-O-S
OSTI Identifier:
1281323
DOI:
https://doi.org/10.17188/1281323

Citation Formats

The Materials Project. Materials Data on KSO2F by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1281323.
The Materials Project. Materials Data on KSO2F by Materials Project. United States. doi:https://doi.org/10.17188/1281323
The Materials Project. 2020. "Materials Data on KSO2F by Materials Project". United States. doi:https://doi.org/10.17188/1281323. https://www.osti.gov/servlets/purl/1281323. Pub date:Thu Jul 16 00:00:00 EDT 2020
@article{osti_1281323,
title = {Materials Data on KSO2F by Materials Project},
author = {The Materials Project},
abstractNote = {KSO2F crystallizes in the monoclinic P2_1/m space group. The structure is three-dimensional. K1+ is bonded in a 9-coordinate geometry to six equivalent O2- and three equivalent F1- atoms. There are four shorter (2.90 Å) and two longer (3.00 Å) K–O bond lengths. There are one shorter (2.85 Å) and two longer (3.18 Å) K–F bond lengths. S4+ is bonded in a trigonal non-coplanar geometry to two equivalent O2- and one F1- atom. Both S–O bond lengths are 1.48 Å. The S–F bond length is 1.83 Å. O2- is bonded in a distorted single-bond geometry to three equivalent K1+ and one S4+ atom. F1- is bonded in a 2-coordinate geometry to three equivalent K1+ and one S4+ atom.},
doi = {10.17188/1281323},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}