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Title: Materials Data on Co4Ge(CO)13 by Materials Project

Abstract

(Co(CO)3)3Co(CO)4Ge crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of six akos016035116 molecules, two germanium molecules, and two Co(CO)4 clusters. In each Co(CO)4 cluster, Co2+ is bonded in a trigonal pyramidal geometry to four C+1.08+ atoms. There is one shorter (1.77 Å) and three longer (1.78 Å) Co–C bond length. There are four inequivalent C+1.08+ sites. In the first C+1.08+ site, C+1.08+ is bonded in a linear geometry to one Co2+ and one O2- atom. The C–O bond length is 1.15 Å. In the second C+1.08+ site, C+1.08+ is bonded in a linear geometry to one Co2+ and one O2- atom. The C–O bond length is 1.16 Å. In the third C+1.08+ site, C+1.08+ is bonded in a linear geometry to one Co2+ and one O2- atom. The C–O bond length is 1.16 Å. In the fourth C+1.08+ site, C+1.08+ is bonded in a linear geometry to one Co2+ and one O2- atom. The C–O bond length is 1.16 Å. There are four inequivalent O2- sites. In the first O2- site, O2- is bonded in a single-bond geometry to one C+1.08+ atom. In the second O2- site, O2- is bonded in a single-bond geometry tomore » one C+1.08+ atom. In the third O2- site, O2- is bonded in a single-bond geometry to one C+1.08+ atom. In the fourth O2- site, O2- is bonded in a single-bond geometry to one C+1.08+ atom.« less

Authors:
Contributors:
Researcher:
Publication Date:
Other Number(s):
mp-652229
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; Co4Ge(CO)13; C-Co-Ge-O
OSTI Identifier:
1281150
DOI:
10.17188/1281150

Citation Formats

Persson, Kristin, and Project, Materials. Materials Data on Co4Ge(CO)13 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1281150.
Persson, Kristin, & Project, Materials. Materials Data on Co4Ge(CO)13 by Materials Project. United States. doi:10.17188/1281150.
Persson, Kristin, and Project, Materials. 2020. "Materials Data on Co4Ge(CO)13 by Materials Project". United States. doi:10.17188/1281150. https://www.osti.gov/servlets/purl/1281150. Pub date:Thu Apr 30 00:00:00 EDT 2020
@article{osti_1281150,
title = {Materials Data on Co4Ge(CO)13 by Materials Project},
author = {Persson, Kristin and Project, Materials},
abstractNote = {(Co(CO)3)3Co(CO)4Ge crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of six akos016035116 molecules, two germanium molecules, and two Co(CO)4 clusters. In each Co(CO)4 cluster, Co2+ is bonded in a trigonal pyramidal geometry to four C+1.08+ atoms. There is one shorter (1.77 Å) and three longer (1.78 Å) Co–C bond length. There are four inequivalent C+1.08+ sites. In the first C+1.08+ site, C+1.08+ is bonded in a linear geometry to one Co2+ and one O2- atom. The C–O bond length is 1.15 Å. In the second C+1.08+ site, C+1.08+ is bonded in a linear geometry to one Co2+ and one O2- atom. The C–O bond length is 1.16 Å. In the third C+1.08+ site, C+1.08+ is bonded in a linear geometry to one Co2+ and one O2- atom. The C–O bond length is 1.16 Å. In the fourth C+1.08+ site, C+1.08+ is bonded in a linear geometry to one Co2+ and one O2- atom. The C–O bond length is 1.16 Å. There are four inequivalent O2- sites. In the first O2- site, O2- is bonded in a single-bond geometry to one C+1.08+ atom. In the second O2- site, O2- is bonded in a single-bond geometry to one C+1.08+ atom. In the third O2- site, O2- is bonded in a single-bond geometry to one C+1.08+ atom. In the fourth O2- site, O2- is bonded in a single-bond geometry to one C+1.08+ atom.},
doi = {10.17188/1281150},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {4}
}

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