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Title: Materials Data on ZnAu2(CN)4 by Materials Project

Abstract

Au2Zn(CN)4 crystallizes in the hexagonal P6_222 space group. The structure is three-dimensional and consists of two Au2Zn(CN)4 frameworks. Au1+ is bonded in a distorted linear geometry to two C2+ atoms. Both Au–C bond lengths are 1.99 Å. Zn2+ is bonded in a tetrahedral geometry to four N3- atoms. All Zn–N bond lengths are 1.98 Å. There are two inequivalent C2+ sites. In the first C2+ site, C2+ is bonded in a distorted single-bond geometry to one Au1+ and one N3- atom. The C–N bond length is 1.17 Å. In the second C2+ site, C2+ is bonded in a distorted single-bond geometry to one Au1+ and one N3- atom. The C–N bond length is 1.17 Å. There are two inequivalent N3- sites. In the first N3- site, N3- is bonded in a linear geometry to one Zn2+ and one C2+ atom. In the second N3- site, N3- is bonded in a linear geometry to one Zn2+ and one C2+ atom.

Publication Date:
Other Number(s):
mp-647252
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; ZnAu2(CN)4; Au-C-N-Zn
OSTI Identifier:
1280687
DOI:
10.17188/1280687

Citation Formats

The Materials Project. Materials Data on ZnAu2(CN)4 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1280687.
The Materials Project. Materials Data on ZnAu2(CN)4 by Materials Project. United States. doi:10.17188/1280687.
The Materials Project. 2020. "Materials Data on ZnAu2(CN)4 by Materials Project". United States. doi:10.17188/1280687. https://www.osti.gov/servlets/purl/1280687. Pub date:Wed Apr 29 00:00:00 EDT 2020
@article{osti_1280687,
title = {Materials Data on ZnAu2(CN)4 by Materials Project},
author = {The Materials Project},
abstractNote = {Au2Zn(CN)4 crystallizes in the hexagonal P6_222 space group. The structure is three-dimensional and consists of two Au2Zn(CN)4 frameworks. Au1+ is bonded in a distorted linear geometry to two C2+ atoms. Both Au–C bond lengths are 1.99 Å. Zn2+ is bonded in a tetrahedral geometry to four N3- atoms. All Zn–N bond lengths are 1.98 Å. There are two inequivalent C2+ sites. In the first C2+ site, C2+ is bonded in a distorted single-bond geometry to one Au1+ and one N3- atom. The C–N bond length is 1.17 Å. In the second C2+ site, C2+ is bonded in a distorted single-bond geometry to one Au1+ and one N3- atom. The C–N bond length is 1.17 Å. There are two inequivalent N3- sites. In the first N3- site, N3- is bonded in a linear geometry to one Zn2+ and one C2+ atom. In the second N3- site, N3- is bonded in a linear geometry to one Zn2+ and one C2+ atom.},
doi = {10.17188/1280687},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {4}
}

Dataset:

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