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Title: Materials Data on Ni(RhO2)2 by Materials Project

Abstract

Ni(RhO2)2 is Spinel structured and crystallizes in the tetragonal I4_1/amd space group. The structure is three-dimensional. Rh3+ is bonded to six equivalent O2- atoms to form RhO6 octahedra that share corners with six equivalent NiO4 tetrahedra and edges with six equivalent RhO6 octahedra. There are two shorter (2.07 Å) and four longer (2.08 Å) Rh–O bond lengths. Ni2+ is bonded to four equivalent O2- atoms to form NiO4 tetrahedra that share corners with twelve equivalent RhO6 octahedra. The corner-sharing octahedra tilt angles range from 52–61°. All Ni–O bond lengths are 2.01 Å. O2- is bonded in a rectangular see-saw-like geometry to three equivalent Rh3+ and one Ni2+ atom.

Publication Date:
Other Number(s):
mp-636519
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; Ni(RhO2)2; Ni-O-Rh
OSTI Identifier:
1279587
DOI:
https://doi.org/10.17188/1279587

Citation Formats

The Materials Project. Materials Data on Ni(RhO2)2 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1279587.
The Materials Project. Materials Data on Ni(RhO2)2 by Materials Project. United States. doi:https://doi.org/10.17188/1279587
The Materials Project. 2020. "Materials Data on Ni(RhO2)2 by Materials Project". United States. doi:https://doi.org/10.17188/1279587. https://www.osti.gov/servlets/purl/1279587. Pub date:Sun May 03 00:00:00 EDT 2020
@article{osti_1279587,
title = {Materials Data on Ni(RhO2)2 by Materials Project},
author = {The Materials Project},
abstractNote = {Ni(RhO2)2 is Spinel structured and crystallizes in the tetragonal I4_1/amd space group. The structure is three-dimensional. Rh3+ is bonded to six equivalent O2- atoms to form RhO6 octahedra that share corners with six equivalent NiO4 tetrahedra and edges with six equivalent RhO6 octahedra. There are two shorter (2.07 Å) and four longer (2.08 Å) Rh–O bond lengths. Ni2+ is bonded to four equivalent O2- atoms to form NiO4 tetrahedra that share corners with twelve equivalent RhO6 octahedra. The corner-sharing octahedra tilt angles range from 52–61°. All Ni–O bond lengths are 2.01 Å. O2- is bonded in a rectangular see-saw-like geometry to three equivalent Rh3+ and one Ni2+ atom.},
doi = {10.17188/1279587},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {5}
}