U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on Mn(ReO4)2 by Materials Project
Abstract
Mn(ReO4)2 crystallizes in the trigonal P-3 space group. The structure is two-dimensional and consists of one Mn(ReO4)2 sheet oriented in the (0, 0, 1) direction. Re7+ is bonded to four O2- atoms to form ReO4 tetrahedra that share corners with three equivalent MnO6 octahedra. The corner-sharing octahedral tilt angles are 16°. There is one shorter (1.73 Å) and three longer (1.76 Å) Re–O bond length. Mn2+ is bonded to six equivalent O2- atoms to form MnO6 octahedra that share corners with six equivalent ReO4 tetrahedra. All Mn–O bond lengths are 2.16 Å. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded in a single-bond geometry to one Re7+ atom. In the second O2- site, O2- is bonded in a distorted linear geometry to one Re7+ and one Mn2+ atom.
- Authors:
- Publication Date:
- Other Number(s):
- mp-627380
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Collaborations:
- MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE
- Keywords:
- crystal structure; Mn(ReO4)2; Mn-O-Re
- OSTI Identifier:
- 1278875
- DOI:
- https://doi.org/10.17188/1278875
Citation Formats
The Materials Project. Materials Data on Mn(ReO4)2 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1278875.
The Materials Project. Materials Data on Mn(ReO4)2 by Materials Project. United States. doi:https://doi.org/10.17188/1278875
The Materials Project. 2020.
"Materials Data on Mn(ReO4)2 by Materials Project". United States. doi:https://doi.org/10.17188/1278875. https://www.osti.gov/servlets/purl/1278875. Pub date:Thu Jul 16 00:00:00 EDT 2020
@article{osti_1278875,
title = {Materials Data on Mn(ReO4)2 by Materials Project},
author = {The Materials Project},
abstractNote = {Mn(ReO4)2 crystallizes in the trigonal P-3 space group. The structure is two-dimensional and consists of one Mn(ReO4)2 sheet oriented in the (0, 0, 1) direction. Re7+ is bonded to four O2- atoms to form ReO4 tetrahedra that share corners with three equivalent MnO6 octahedra. The corner-sharing octahedral tilt angles are 16°. There is one shorter (1.73 Å) and three longer (1.76 Å) Re–O bond length. Mn2+ is bonded to six equivalent O2- atoms to form MnO6 octahedra that share corners with six equivalent ReO4 tetrahedra. All Mn–O bond lengths are 2.16 Å. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded in a single-bond geometry to one Re7+ atom. In the second O2- site, O2- is bonded in a distorted linear geometry to one Re7+ and one Mn2+ atom.},
doi = {10.17188/1278875},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}