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Title: Materials Data on EuCo8P5 by Materials Project

Abstract

EuCo8P5 crystallizes in the orthorhombic Pmmn space group. The structure is three-dimensional. Eu2+ is bonded in a distorted body-centered cubic geometry to eight P3- atoms. There are four shorter (3.06 Å) and four longer (3.13 Å) Eu–P bond lengths. There are five inequivalent Co+1.62+ sites. In the first Co+1.62+ site, Co+1.62+ is bonded to four P3- atoms to form a mixture of edge and corner-sharing CoP4 tetrahedra. There are a spread of Co–P bond distances ranging from 2.16–2.24 Å. In the second Co+1.62+ site, Co+1.62+ is bonded to four P3- atoms to form a mixture of edge and corner-sharing CoP4 tetrahedra. There are two shorter (2.28 Å) and two longer (2.30 Å) Co–P bond lengths. In the third Co+1.62+ site, Co+1.62+ is bonded to four P3- atoms to form a mixture of edge and corner-sharing CoP4 tetrahedra. There are a spread of Co–P bond distances ranging from 2.17–2.24 Å. In the fourth Co+1.62+ site, Co+1.62+ is bonded in a 5-coordinate geometry to five P3- atoms. There are one shorter (2.18 Å) and four longer (2.30 Å) Co–P bond lengths. In the fifth Co+1.62+ site, Co+1.62+ is bonded in a 5-coordinate geometry to five P3- atoms. There are a spread ofmore » Co–P bond distances ranging from 2.20–2.53 Å. There are three inequivalent P3- sites. In the first P3- site, P3- is bonded in a 9-coordinate geometry to two equivalent Eu2+ and seven Co+1.62+ atoms. In the second P3- site, P3- is bonded in a 6-coordinate geometry to two equivalent Eu2+ and six Co+1.62+ atoms. In the third P3- site, P3- is bonded in a 9-coordinate geometry to nine Co+1.62+ atoms.« less

Authors:
Publication Date:
Other Number(s):
mp-583224
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Collaborations:
MIT; UC Berkeley; Duke; U Louvain
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; EuCo8P5; Co-Eu-P
OSTI Identifier:
1277045
DOI:
https://doi.org/10.17188/1277045

Citation Formats

The Materials Project. Materials Data on EuCo8P5 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1277045.
The Materials Project. Materials Data on EuCo8P5 by Materials Project. United States. doi:https://doi.org/10.17188/1277045
The Materials Project. 2020. "Materials Data on EuCo8P5 by Materials Project". United States. doi:https://doi.org/10.17188/1277045. https://www.osti.gov/servlets/purl/1277045. Pub date:Mon Aug 03 00:00:00 EDT 2020
@article{osti_1277045,
title = {Materials Data on EuCo8P5 by Materials Project},
author = {The Materials Project},
abstractNote = {EuCo8P5 crystallizes in the orthorhombic Pmmn space group. The structure is three-dimensional. Eu2+ is bonded in a distorted body-centered cubic geometry to eight P3- atoms. There are four shorter (3.06 Å) and four longer (3.13 Å) Eu–P bond lengths. There are five inequivalent Co+1.62+ sites. In the first Co+1.62+ site, Co+1.62+ is bonded to four P3- atoms to form a mixture of edge and corner-sharing CoP4 tetrahedra. There are a spread of Co–P bond distances ranging from 2.16–2.24 Å. In the second Co+1.62+ site, Co+1.62+ is bonded to four P3- atoms to form a mixture of edge and corner-sharing CoP4 tetrahedra. There are two shorter (2.28 Å) and two longer (2.30 Å) Co–P bond lengths. In the third Co+1.62+ site, Co+1.62+ is bonded to four P3- atoms to form a mixture of edge and corner-sharing CoP4 tetrahedra. There are a spread of Co–P bond distances ranging from 2.17–2.24 Å. In the fourth Co+1.62+ site, Co+1.62+ is bonded in a 5-coordinate geometry to five P3- atoms. There are one shorter (2.18 Å) and four longer (2.30 Å) Co–P bond lengths. In the fifth Co+1.62+ site, Co+1.62+ is bonded in a 5-coordinate geometry to five P3- atoms. There are a spread of Co–P bond distances ranging from 2.20–2.53 Å. There are three inequivalent P3- sites. In the first P3- site, P3- is bonded in a 9-coordinate geometry to two equivalent Eu2+ and seven Co+1.62+ atoms. In the second P3- site, P3- is bonded in a 6-coordinate geometry to two equivalent Eu2+ and six Co+1.62+ atoms. In the third P3- site, P3- is bonded in a 9-coordinate geometry to nine Co+1.62+ atoms.},
doi = {10.17188/1277045},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {8}
}