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Title: Materials Data on KAg(CN)2 by Materials Project

Abstract

KAg(CN)2 is Potassium Silver Cyanide structured and crystallizes in the trigonal P-31c space group. The structure is three-dimensional. there are two inequivalent K1+ sites. In the first K1+ site, K1+ is bonded to six equivalent N3- atoms to form edge-sharing KN6 octahedra. There are three shorter (2.86 Å) and three longer (2.98 Å) K–N bond lengths. In the second K1+ site, K1+ is bonded to six equivalent N3- atoms to form edge-sharing KN6 octahedra. All K–N bond lengths are 2.92 Å. Ag1+ is bonded in a linear geometry to two equivalent C2+ atoms. Both Ag–C bond lengths are 2.05 Å. C2+ is bonded in a linear geometry to one Ag1+ and one N3- atom. The C–N bond length is 1.17 Å. N3- is bonded in a 4-coordinate geometry to three K1+ and one C2+ atom.

Publication Date:
Other Number(s):
mp-582994
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; KAg(CN)2; Ag-C-K-N
OSTI Identifier:
1277024
DOI:
https://doi.org/10.17188/1277024

Citation Formats

The Materials Project. Materials Data on KAg(CN)2 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1277024.
The Materials Project. Materials Data on KAg(CN)2 by Materials Project. United States. doi:https://doi.org/10.17188/1277024
The Materials Project. 2020. "Materials Data on KAg(CN)2 by Materials Project". United States. doi:https://doi.org/10.17188/1277024. https://www.osti.gov/servlets/purl/1277024. Pub date:Wed Apr 29 00:00:00 EDT 2020
@article{osti_1277024,
title = {Materials Data on KAg(CN)2 by Materials Project},
author = {The Materials Project},
abstractNote = {KAg(CN)2 is Potassium Silver Cyanide structured and crystallizes in the trigonal P-31c space group. The structure is three-dimensional. there are two inequivalent K1+ sites. In the first K1+ site, K1+ is bonded to six equivalent N3- atoms to form edge-sharing KN6 octahedra. There are three shorter (2.86 Å) and three longer (2.98 Å) K–N bond lengths. In the second K1+ site, K1+ is bonded to six equivalent N3- atoms to form edge-sharing KN6 octahedra. All K–N bond lengths are 2.92 Å. Ag1+ is bonded in a linear geometry to two equivalent C2+ atoms. Both Ag–C bond lengths are 2.05 Å. C2+ is bonded in a linear geometry to one Ag1+ and one N3- atom. The C–N bond length is 1.17 Å. N3- is bonded in a 4-coordinate geometry to three K1+ and one C2+ atom.},
doi = {10.17188/1277024},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {4}
}