Materials Data on KAg(CN)2 by Materials Project

doi:10.17188/1277024

Title: Materials Data on KAg(CN)2 by Materials Project

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Abstract

KAg(CN)2 is Potassium Silver Cyanide structured and crystallizes in the trigonal P-31c space group. The structure is three-dimensional. there are two inequivalent K1+ sites. In the first K1+ site, K1+ is bonded to six equivalent N3- atoms to form edge-sharing KN6 octahedra. There are three shorter (2.86 Å) and three longer (2.98 Å) K–N bond lengths. In the second K1+ site, K1+ is bonded to six equivalent N3- atoms to form edge-sharing KN6 octahedra. All K–N bond lengths are 2.92 Å. Ag1+ is bonded in a linear geometry to two equivalent C2+ atoms. Both Ag–C bond lengths are 2.05 Å. C2+ is bonded in a linear geometry to one Ag1+ and one N3- atom. The C–N bond length is 1.17 Å. N3- is bonded in a 4-coordinate geometry to three K1+ and one C2+ atom.

Authors:: The Materials Project

Publication Date:: 2020-04-29

Other Number(s):: mp-582994

DOE Contract Number:: AC02-05CH11231; EDCBEE

Research Org.:: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Collaborations:: MIT; UC Berkeley; Duke; U Louvain

Subject:: 36 MATERIALS SCIENCE

Keywords:: crystal structure; KAg(CN)2; Ag-C-K-N

OSTI Identifier:: 1277024

DOI:: https://doi.org/10.17188/1277024

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                    The Materials Project. Materials Data on KAg(CN)2 by Materials Project.  United States: N. p., 2020. 
        Web.  doi:10.17188/1277024.

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                    The Materials Project. Materials Data on KAg(CN)2 by Materials Project.  United States.  doi:https://doi.org/10.17188/1277024

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                    The Materials Project. 2020.  
"Materials Data on KAg(CN)2 by Materials Project".  United States.  doi:https://doi.org/10.17188/1277024.  https://www.osti.gov/servlets/purl/1277024. Pub date:Wed Apr 29 00:00:00 EDT 2020

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@article{osti_1277024,

  title        = {Materials Data on KAg(CN)2 by Materials Project},

  author       = {The Materials Project},

  abstractNote = {KAg(CN)2 is Potassium Silver Cyanide structured and crystallizes in the trigonal P-31c space group. The structure is three-dimensional. there are two inequivalent K1+ sites. In the first K1+ site, K1+ is bonded to six equivalent N3- atoms to form edge-sharing KN6 octahedra. There are three shorter (2.86 Å) and three longer (2.98 Å) K–N bond lengths. In the second K1+ site, K1+ is bonded to six equivalent N3- atoms to form edge-sharing KN6 octahedra. All K–N bond lengths are 2.92 Å. Ag1+ is bonded in a linear geometry to two equivalent C2+ atoms. Both Ag–C bond lengths are 2.05 Å. C2+ is bonded in a linear geometry to one Ag1+ and one N3- atom. The C–N bond length is 1.17 Å. N3- is bonded in a 4-coordinate geometry to three K1+ and one C2+ atom.},

  doi          = {10.17188/1277024},

  journal      = {},

  number       = ,

  volume       = ,

  place        = {United States},

  year         = {2020},

  month        = {4}

}

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DOI: https://doi.org/10.17188/1277024

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