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Title: Materials Data on EuNi5P3 by Materials Project

Abstract

EuNi5P3 crystallizes in the orthorhombic Cmcm space group. The structure is three-dimensional. Eu2+ is bonded in a 7-coordinate geometry to seven P3- atoms. There are a spread of Eu–P bond distances ranging from 3.05–3.26 Å. There are three inequivalent Ni+1.40+ sites. In the first Ni+1.40+ site, Ni+1.40+ is bonded to four P3- atoms to form a mixture of edge and corner-sharing NiP4 tetrahedra. There are a spread of Ni–P bond distances ranging from 2.27–2.32 Å. In the second Ni+1.40+ site, Ni+1.40+ is bonded to four P3- atoms to form a mixture of edge and corner-sharing NiP4 tetrahedra. There are a spread of Ni–P bond distances ranging from 2.17–2.38 Å. In the third Ni+1.40+ site, Ni+1.40+ is bonded in a square co-planar geometry to four equivalent P3- atoms. All Ni–P bond lengths are 2.32 Å. There are two inequivalent P3- sites. In the first P3- site, P3- is bonded in a 9-coordinate geometry to three equivalent Eu2+ and six Ni+1.40+ atoms. In the second P3- site, P3- is bonded in a 9-coordinate geometry to two equivalent Eu2+ and seven Ni+1.40+ atoms.

Authors:
Publication Date:
Other Number(s):
mp-582367
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Collaborations:
MIT; UC Berkeley; Duke; U Louvain
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; EuNi5P3; Eu-Ni-P
OSTI Identifier:
1276971
DOI:
https://doi.org/10.17188/1276971

Citation Formats

The Materials Project. Materials Data on EuNi5P3 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1276971.
The Materials Project. Materials Data on EuNi5P3 by Materials Project. United States. doi:https://doi.org/10.17188/1276971
The Materials Project. 2020. "Materials Data on EuNi5P3 by Materials Project". United States. doi:https://doi.org/10.17188/1276971. https://www.osti.gov/servlets/purl/1276971. Pub date:Wed Jun 24 00:00:00 EDT 2020
@article{osti_1276971,
title = {Materials Data on EuNi5P3 by Materials Project},
author = {The Materials Project},
abstractNote = {EuNi5P3 crystallizes in the orthorhombic Cmcm space group. The structure is three-dimensional. Eu2+ is bonded in a 7-coordinate geometry to seven P3- atoms. There are a spread of Eu–P bond distances ranging from 3.05–3.26 Å. There are three inequivalent Ni+1.40+ sites. In the first Ni+1.40+ site, Ni+1.40+ is bonded to four P3- atoms to form a mixture of edge and corner-sharing NiP4 tetrahedra. There are a spread of Ni–P bond distances ranging from 2.27–2.32 Å. In the second Ni+1.40+ site, Ni+1.40+ is bonded to four P3- atoms to form a mixture of edge and corner-sharing NiP4 tetrahedra. There are a spread of Ni–P bond distances ranging from 2.17–2.38 Å. In the third Ni+1.40+ site, Ni+1.40+ is bonded in a square co-planar geometry to four equivalent P3- atoms. All Ni–P bond lengths are 2.32 Å. There are two inequivalent P3- sites. In the first P3- site, P3- is bonded in a 9-coordinate geometry to three equivalent Eu2+ and six Ni+1.40+ atoms. In the second P3- site, P3- is bonded in a 9-coordinate geometry to two equivalent Eu2+ and seven Ni+1.40+ atoms.},
doi = {10.17188/1276971},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {6}
}