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Title: Materials Data on Bi14Rh3 by Materials Project

Abstract

Rh3Bi14 crystallizes in the orthorhombic Fddd space group. The structure is three-dimensional. there are two inequivalent Rh sites. In the first Rh site, Rh is bonded in a body-centered cubic geometry to eight Bi atoms. There are a spread of Rh–Bi bond distances ranging from 2.88–2.95 Å. In the second Rh site, Rh is bonded in a 8-coordinate geometry to eight Bi atoms. There are four shorter (2.85 Å) and four longer (2.91 Å) Rh–Bi bond lengths. There are four inequivalent Bi sites. In the first Bi site, Bi is bonded in a distorted water-like geometry to two Rh and one Bi atom. The Bi–Bi bond length is 3.61 Å. In the second Bi site, Bi is bonded in a distorted water-like geometry to two equivalent Rh and one Bi atom. The Bi–Bi bond length is 3.49 Å. In the third Bi site, Bi is bonded in a 10-coordinate geometry to ten Bi atoms. There are a spread of Bi–Bi bond distances ranging from 3.43–3.59 Å. In the fourth Bi site, Bi is bonded in a distorted water-like geometry to two Rh and two equivalent Bi atoms.

Publication Date:
Other Number(s):
mp-581527
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; Bi14Rh3; Bi-Rh
OSTI Identifier:
1276856
DOI:
https://doi.org/10.17188/1276856

Citation Formats

The Materials Project. Materials Data on Bi14Rh3 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1276856.
The Materials Project. Materials Data on Bi14Rh3 by Materials Project. United States. doi:https://doi.org/10.17188/1276856
The Materials Project. 2020. "Materials Data on Bi14Rh3 by Materials Project". United States. doi:https://doi.org/10.17188/1276856. https://www.osti.gov/servlets/purl/1276856. Pub date:Thu Apr 30 00:00:00 EDT 2020
@article{osti_1276856,
title = {Materials Data on Bi14Rh3 by Materials Project},
author = {The Materials Project},
abstractNote = {Rh3Bi14 crystallizes in the orthorhombic Fddd space group. The structure is three-dimensional. there are two inequivalent Rh sites. In the first Rh site, Rh is bonded in a body-centered cubic geometry to eight Bi atoms. There are a spread of Rh–Bi bond distances ranging from 2.88–2.95 Å. In the second Rh site, Rh is bonded in a 8-coordinate geometry to eight Bi atoms. There are four shorter (2.85 Å) and four longer (2.91 Å) Rh–Bi bond lengths. There are four inequivalent Bi sites. In the first Bi site, Bi is bonded in a distorted water-like geometry to two Rh and one Bi atom. The Bi–Bi bond length is 3.61 Å. In the second Bi site, Bi is bonded in a distorted water-like geometry to two equivalent Rh and one Bi atom. The Bi–Bi bond length is 3.49 Å. In the third Bi site, Bi is bonded in a 10-coordinate geometry to ten Bi atoms. There are a spread of Bi–Bi bond distances ranging from 3.43–3.59 Å. In the fourth Bi site, Bi is bonded in a distorted water-like geometry to two Rh and two equivalent Bi atoms.},
doi = {10.17188/1276856},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {4}
}