skip to main content
DOE Data Explorer title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Materials Data on Ce3(AgSn)4 by Materials Project

Abstract

Ce3Ag4Sn4 crystallizes in the orthorhombic Immm space group. The structure is three-dimensional. there are two inequivalent Ce sites. In the first Ce site, Ce is bonded in a 2-coordinate geometry to six equivalent Ag and four Sn atoms. There are four shorter (3.44 Å) and two longer (3.71 Å) Ce–Ag bond lengths. There are two shorter (3.08 Å) and two longer (3.27 Å) Ce–Sn bond lengths. In the second Ce site, Ce is bonded to eight equivalent Ag and four Sn atoms to form distorted face-sharing CeAg8Sn4 cuboctahedra. All Ce–Ag bond lengths are 3.45 Å. There are two shorter (2.88 Å) and two longer (3.12 Å) Ce–Sn bond lengths. Ag is bonded in a 9-coordinate geometry to five Ce and four Sn atoms. There are two shorter (2.99 Å) and two longer (3.18 Å) Ag–Sn bond lengths. There are two inequivalent Sn sites. In the first Sn site, Sn is bonded in a 7-coordinate geometry to three Ce and four equivalent Ag atoms. In the second Sn site, Sn is bonded in a 1-coordinate geometry to three Ce, four equivalent Ag, and one Sn atom. The Sn–Sn bond length is 2.71 Å.

Publication Date:
Other Number(s):
mp-581496
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; Ce3(AgSn)4; Ag-Ce-Sn
OSTI Identifier:
1276853
DOI:
https://doi.org/10.17188/1276853

Citation Formats

The Materials Project. Materials Data on Ce3(AgSn)4 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1276853.
The Materials Project. Materials Data on Ce3(AgSn)4 by Materials Project. United States. doi:https://doi.org/10.17188/1276853
The Materials Project. 2020. "Materials Data on Ce3(AgSn)4 by Materials Project". United States. doi:https://doi.org/10.17188/1276853. https://www.osti.gov/servlets/purl/1276853. Pub date:Wed Jul 22 00:00:00 EDT 2020
@article{osti_1276853,
title = {Materials Data on Ce3(AgSn)4 by Materials Project},
author = {The Materials Project},
abstractNote = {Ce3Ag4Sn4 crystallizes in the orthorhombic Immm space group. The structure is three-dimensional. there are two inequivalent Ce sites. In the first Ce site, Ce is bonded in a 2-coordinate geometry to six equivalent Ag and four Sn atoms. There are four shorter (3.44 Å) and two longer (3.71 Å) Ce–Ag bond lengths. There are two shorter (3.08 Å) and two longer (3.27 Å) Ce–Sn bond lengths. In the second Ce site, Ce is bonded to eight equivalent Ag and four Sn atoms to form distorted face-sharing CeAg8Sn4 cuboctahedra. All Ce–Ag bond lengths are 3.45 Å. There are two shorter (2.88 Å) and two longer (3.12 Å) Ce–Sn bond lengths. Ag is bonded in a 9-coordinate geometry to five Ce and four Sn atoms. There are two shorter (2.99 Å) and two longer (3.18 Å) Ag–Sn bond lengths. There are two inequivalent Sn sites. In the first Sn site, Sn is bonded in a 7-coordinate geometry to three Ce and four equivalent Ag atoms. In the second Sn site, Sn is bonded in a 1-coordinate geometry to three Ce, four equivalent Ag, and one Sn atom. The Sn–Sn bond length is 2.71 Å.},
doi = {10.17188/1276853},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}