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Title: Materials Data on Ag2CN2 by Materials Project

Abstract

Ag2NCN is Potassium Silver Cyanide-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is three-dimensional. there are three inequivalent Ag1+ sites. In the first Ag1+ site, Ag1+ is bonded in a 4-coordinate geometry to four N3- atoms. There are a spread of Ag–N bond distances ranging from 2.19–2.89 Å. In the second Ag1+ site, Ag1+ is bonded in a linear geometry to two equivalent N3- atoms. Both Ag–N bond lengths are 2.15 Å. In the third Ag1+ site, Ag1+ is bonded in a linear geometry to two equivalent N3- atoms. Both Ag–N bond lengths are 2.17 Å. C4+ is bonded in a linear geometry to two N3- atoms. There is one shorter (1.21 Å) and one longer (1.27 Å) C–N bond length. There are two inequivalent N3- sites. In the first N3- site, N3- is bonded to three Ag1+ and one C4+ atom to form corner-sharing NAg3C tetrahedra. In the second N3- site, N3- is bonded in a 1-coordinate geometry to three equivalent Ag1+ and one C4+ atom.

Publication Date:
Other Number(s):
mp-574486
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; Ag2CN2; Ag-C-N
OSTI Identifier:
1276584
DOI:
10.17188/1276584

Citation Formats

The Materials Project. Materials Data on Ag2CN2 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1276584.
The Materials Project. Materials Data on Ag2CN2 by Materials Project. United States. doi:10.17188/1276584.
The Materials Project. 2020. "Materials Data on Ag2CN2 by Materials Project". United States. doi:10.17188/1276584. https://www.osti.gov/servlets/purl/1276584. Pub date:Fri Jul 17 00:00:00 EDT 2020
@article{osti_1276584,
title = {Materials Data on Ag2CN2 by Materials Project},
author = {The Materials Project},
abstractNote = {Ag2NCN is Potassium Silver Cyanide-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is three-dimensional. there are three inequivalent Ag1+ sites. In the first Ag1+ site, Ag1+ is bonded in a 4-coordinate geometry to four N3- atoms. There are a spread of Ag–N bond distances ranging from 2.19–2.89 Å. In the second Ag1+ site, Ag1+ is bonded in a linear geometry to two equivalent N3- atoms. Both Ag–N bond lengths are 2.15 Å. In the third Ag1+ site, Ag1+ is bonded in a linear geometry to two equivalent N3- atoms. Both Ag–N bond lengths are 2.17 Å. C4+ is bonded in a linear geometry to two N3- atoms. There is one shorter (1.21 Å) and one longer (1.27 Å) C–N bond length. There are two inequivalent N3- sites. In the first N3- site, N3- is bonded to three Ag1+ and one C4+ atom to form corner-sharing NAg3C tetrahedra. In the second N3- site, N3- is bonded in a 1-coordinate geometry to three equivalent Ag1+ and one C4+ atom.},
doi = {10.17188/1276584},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}

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