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Title: Materials Data on Tl2Hg2PdCl8 by Materials Project

Abstract

PdHg2Tl2Cl8 crystallizes in the monoclinic C2/m space group. The structure is three-dimensional. Pd2+ is bonded in a square co-planar geometry to four equivalent Cl1- atoms. All Pd–Cl bond lengths are 2.33 Å. Hg2+ is bonded in a distorted linear geometry to four Cl1- atoms. There are a spread of Hg–Cl bond distances ranging from 2.34–3.23 Å. Tl1+ is bonded in a 10-coordinate geometry to ten Cl1- atoms. There are a spread of Tl–Cl bond distances ranging from 3.34–3.77 Å. There are three inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded in a 1-coordinate geometry to one Pd2+, one Hg2+, and three equivalent Tl1+ atoms. In the second Cl1- site, Cl1- is bonded in a distorted single-bond geometry to one Hg2+ and two equivalent Tl1+ atoms. In the third Cl1- site, Cl1- is bonded in a distorted single-bond geometry to one Hg2+ and two equivalent Tl1+ atoms.

Publication Date:
Other Number(s):
mp-569675
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; Tl2Hg2PdCl8; Cl-Hg-Pd-Tl
OSTI Identifier:
1275206
DOI:
10.17188/1275206

Citation Formats

The Materials Project. Materials Data on Tl2Hg2PdCl8 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1275206.
The Materials Project. Materials Data on Tl2Hg2PdCl8 by Materials Project. United States. doi:10.17188/1275206.
The Materials Project. 2020. "Materials Data on Tl2Hg2PdCl8 by Materials Project". United States. doi:10.17188/1275206. https://www.osti.gov/servlets/purl/1275206. Pub date:Tue Jul 14 00:00:00 EDT 2020
@article{osti_1275206,
title = {Materials Data on Tl2Hg2PdCl8 by Materials Project},
author = {The Materials Project},
abstractNote = {PdHg2Tl2Cl8 crystallizes in the monoclinic C2/m space group. The structure is three-dimensional. Pd2+ is bonded in a square co-planar geometry to four equivalent Cl1- atoms. All Pd–Cl bond lengths are 2.33 Å. Hg2+ is bonded in a distorted linear geometry to four Cl1- atoms. There are a spread of Hg–Cl bond distances ranging from 2.34–3.23 Å. Tl1+ is bonded in a 10-coordinate geometry to ten Cl1- atoms. There are a spread of Tl–Cl bond distances ranging from 3.34–3.77 Å. There are three inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded in a 1-coordinate geometry to one Pd2+, one Hg2+, and three equivalent Tl1+ atoms. In the second Cl1- site, Cl1- is bonded in a distorted single-bond geometry to one Hg2+ and two equivalent Tl1+ atoms. In the third Cl1- site, Cl1- is bonded in a distorted single-bond geometry to one Hg2+ and two equivalent Tl1+ atoms.},
doi = {10.17188/1275206},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}

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