U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on RbLaSi(CN2)4 by Materials Project
Abstract
RbLaSi(CN2)4 crystallizes in the tetragonal I-4 space group. The structure is three-dimensional. Rb1+ is bonded in a 8-coordinate geometry to eight N3- atoms. There are four shorter (3.46 Å) and four longer (3.53 Å) Rb–N bond lengths. La3+ is bonded in a 8-coordinate geometry to eight N3- atoms. There are four shorter (2.55 Å) and four longer (2.71 Å) La–N bond lengths. Si4+ is bonded in a tetrahedral geometry to four equivalent N3- atoms. All Si–N bond lengths are 1.73 Å. C4+ is bonded in a linear geometry to two N3- atoms. There is one shorter (1.20 Å) and one longer (1.27 Å) C–N bond length. There are two inequivalent N3- sites. In the first N3- site, N3- is bonded in a distorted bent 150 degrees geometry to one Rb1+, one La3+, and one C4+ atom. In the second N3- site, N3- is bonded in a distorted bent 120 degrees geometry to one Rb1+, one La3+, one Si4+, and one C4+ atom.
- Publication Date:
- Other Number(s):
- mp-568228
- DOE Contract Number:
- AC02-05CH11231
- Research Org.:
- LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- Collaborations:
- The Materials Project; MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE; C-La-N-Rb-Si; RbLaSi(CN2)4; crystal structure
- OSTI Identifier:
- 1274302
- DOI:
- https://doi.org/10.17188/1274302
Citation Formats
Materials Data on RbLaSi(CN2)4 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1274302.
Materials Data on RbLaSi(CN2)4 by Materials Project. United States. doi:https://doi.org/10.17188/1274302
2020.
"Materials Data on RbLaSi(CN2)4 by Materials Project". United States. doi:https://doi.org/10.17188/1274302. https://www.osti.gov/servlets/purl/1274302. Pub date:Sat May 09 04:00:00 UTC 2020
@article{osti_1274302,
title = {Materials Data on RbLaSi(CN2)4 by Materials Project},
abstractNote = {RbLaSi(CN2)4 crystallizes in the tetragonal I-4 space group. The structure is three-dimensional. Rb1+ is bonded in a 8-coordinate geometry to eight N3- atoms. There are four shorter (3.46 Å) and four longer (3.53 Å) Rb–N bond lengths. La3+ is bonded in a 8-coordinate geometry to eight N3- atoms. There are four shorter (2.55 Å) and four longer (2.71 Å) La–N bond lengths. Si4+ is bonded in a tetrahedral geometry to four equivalent N3- atoms. All Si–N bond lengths are 1.73 Å. C4+ is bonded in a linear geometry to two N3- atoms. There is one shorter (1.20 Å) and one longer (1.27 Å) C–N bond length. There are two inequivalent N3- sites. In the first N3- site, N3- is bonded in a distorted bent 150 degrees geometry to one Rb1+, one La3+, and one C4+ atom. In the second N3- site, N3- is bonded in a distorted bent 120 degrees geometry to one Rb1+, one La3+, one Si4+, and one C4+ atom.},
doi = {10.17188/1274302},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {5}
}