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Title: Materials Data on RbLaSi(CN2)4 by Materials Project

Abstract

RbLaSi(CN2)4 crystallizes in the tetragonal I-4 space group. The structure is three-dimensional. Rb1+ is bonded in a 8-coordinate geometry to eight N3- atoms. There are four shorter (3.46 Å) and four longer (3.53 Å) Rb–N bond lengths. La3+ is bonded in a 8-coordinate geometry to eight N3- atoms. There are four shorter (2.55 Å) and four longer (2.71 Å) La–N bond lengths. Si4+ is bonded in a tetrahedral geometry to four equivalent N3- atoms. All Si–N bond lengths are 1.73 Å. C4+ is bonded in a linear geometry to two N3- atoms. There is one shorter (1.20 Å) and one longer (1.27 Å) C–N bond length. There are two inequivalent N3- sites. In the first N3- site, N3- is bonded in a distorted bent 150 degrees geometry to one Rb1+, one La3+, and one C4+ atom. In the second N3- site, N3- is bonded in a distorted bent 120 degrees geometry to one Rb1+, one La3+, one Si4+, and one C4+ atom.

Publication Date:
Other Number(s):
mp-568228
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; RbLaSi(CN2)4; C-La-N-Rb-Si
OSTI Identifier:
1274302
DOI:
https://doi.org/10.17188/1274302

Citation Formats

The Materials Project. Materials Data on RbLaSi(CN2)4 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1274302.
The Materials Project. Materials Data on RbLaSi(CN2)4 by Materials Project. United States. doi:https://doi.org/10.17188/1274302
The Materials Project. 2020. "Materials Data on RbLaSi(CN2)4 by Materials Project". United States. doi:https://doi.org/10.17188/1274302. https://www.osti.gov/servlets/purl/1274302. Pub date:Sat May 09 00:00:00 EDT 2020
@article{osti_1274302,
title = {Materials Data on RbLaSi(CN2)4 by Materials Project},
author = {The Materials Project},
abstractNote = {RbLaSi(CN2)4 crystallizes in the tetragonal I-4 space group. The structure is three-dimensional. Rb1+ is bonded in a 8-coordinate geometry to eight N3- atoms. There are four shorter (3.46 Å) and four longer (3.53 Å) Rb–N bond lengths. La3+ is bonded in a 8-coordinate geometry to eight N3- atoms. There are four shorter (2.55 Å) and four longer (2.71 Å) La–N bond lengths. Si4+ is bonded in a tetrahedral geometry to four equivalent N3- atoms. All Si–N bond lengths are 1.73 Å. C4+ is bonded in a linear geometry to two N3- atoms. There is one shorter (1.20 Å) and one longer (1.27 Å) C–N bond length. There are two inequivalent N3- sites. In the first N3- site, N3- is bonded in a distorted bent 150 degrees geometry to one Rb1+, one La3+, and one C4+ atom. In the second N3- site, N3- is bonded in a distorted bent 120 degrees geometry to one Rb1+, one La3+, one Si4+, and one C4+ atom.},
doi = {10.17188/1274302},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {5}
}