U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on SbH16C4N2Cl5 by Materials Project
Abstract
((CH3)2NH2)2SbCl5 is Silicon tetrafluoride-derived structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of eight dimethylazanium molecules and four SbCl5 clusters. In each SbCl5 cluster, Sb3+ is bonded in a square pyramidal geometry to five Cl1- atoms. There are a spread of Sb–Cl bond distances ranging from 2.43–2.90 Å. There are four inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded in a single-bond geometry to one Sb3+ atom. In the second Cl1- site, Cl1- is bonded in a single-bond geometry to one Sb3+ atom. In the third Cl1- site, Cl1- is bonded in a single-bond geometry to one Sb3+ atom. In the fourth Cl1- site, Cl1- is bonded in a single-bond geometry to one Sb3+ atom.
- Publication Date:
- Other Number(s):
- mp-571548
- DOE Contract Number:
- AC02-05CH11231
- Research Org.:
- LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- Collaborations:
- The Materials Project; MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE; C-Cl-H-N-Sb; SbH16C4N2Cl5; crystal structure
- OSTI Identifier:
- 1272921
- DOI:
- https://doi.org/10.17188/1272921
Citation Formats
Materials Data on SbH16C4N2Cl5 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1272921.
Materials Data on SbH16C4N2Cl5 by Materials Project. United States. doi:https://doi.org/10.17188/1272921
2020.
"Materials Data on SbH16C4N2Cl5 by Materials Project". United States. doi:https://doi.org/10.17188/1272921. https://www.osti.gov/servlets/purl/1272921. Pub date:Sat May 30 00:00:00 EDT 2020
@article{osti_1272921,
title = {Materials Data on SbH16C4N2Cl5 by Materials Project},
abstractNote = {((CH3)2NH2)2SbCl5 is Silicon tetrafluoride-derived structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of eight dimethylazanium molecules and four SbCl5 clusters. In each SbCl5 cluster, Sb3+ is bonded in a square pyramidal geometry to five Cl1- atoms. There are a spread of Sb–Cl bond distances ranging from 2.43–2.90 Å. There are four inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded in a single-bond geometry to one Sb3+ atom. In the second Cl1- site, Cl1- is bonded in a single-bond geometry to one Sb3+ atom. In the third Cl1- site, Cl1- is bonded in a single-bond geometry to one Sb3+ atom. In the fourth Cl1- site, Cl1- is bonded in a single-bond geometry to one Sb3+ atom.},
doi = {10.17188/1272921},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {5}
}