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Title: Materials Data on Ag3F8 by Materials Project

Abstract

Ag(AgF4)2 crystallizes in the monoclinic P2_1/c space group. The structure is three-dimensional. there are two inequivalent Ag+2.67+ sites. In the first Ag+2.67+ site, Ag+2.67+ is bonded in a rectangular see-saw-like geometry to four F1- atoms. There is two shorter (1.96 Å) and two longer (2.00 Å) Ag–F bond length. In the second Ag+2.67+ site, Ag+2.67+ is bonded in a distorted octahedral geometry to six F1- atoms. There are a spread of Ag–F bond distances ranging from 2.12–2.58 Å. There are four inequivalent F1- sites. In the first F1- site, F1- is bonded in a distorted bent 120 degrees geometry to two Ag+2.67+ atoms. In the second F1- site, F1- is bonded in a single-bond geometry to one Ag+2.67+ atom. In the third F1- site, F1- is bonded in a bent 120 degrees geometry to two Ag+2.67+ atoms. In the fourth F1- site, F1- is bonded in a distorted single-bond geometry to two Ag+2.67+ atoms.

Authors:
Publication Date:
Other Number(s):
mp-562412
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Collaborations:
MIT; UC Berkeley; Duke; U Louvain
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; Ag3F8; Ag-F
OSTI Identifier:
1272341
DOI:
https://doi.org/10.17188/1272341

Citation Formats

The Materials Project. Materials Data on Ag3F8 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1272341.
The Materials Project. Materials Data on Ag3F8 by Materials Project. United States. doi:https://doi.org/10.17188/1272341
The Materials Project. 2020. "Materials Data on Ag3F8 by Materials Project". United States. doi:https://doi.org/10.17188/1272341. https://www.osti.gov/servlets/purl/1272341. Pub date:Wed Jul 15 00:00:00 EDT 2020
@article{osti_1272341,
title = {Materials Data on Ag3F8 by Materials Project},
author = {The Materials Project},
abstractNote = {Ag(AgF4)2 crystallizes in the monoclinic P2_1/c space group. The structure is three-dimensional. there are two inequivalent Ag+2.67+ sites. In the first Ag+2.67+ site, Ag+2.67+ is bonded in a rectangular see-saw-like geometry to four F1- atoms. There is two shorter (1.96 Å) and two longer (2.00 Å) Ag–F bond length. In the second Ag+2.67+ site, Ag+2.67+ is bonded in a distorted octahedral geometry to six F1- atoms. There are a spread of Ag–F bond distances ranging from 2.12–2.58 Å. There are four inequivalent F1- sites. In the first F1- site, F1- is bonded in a distorted bent 120 degrees geometry to two Ag+2.67+ atoms. In the second F1- site, F1- is bonded in a single-bond geometry to one Ag+2.67+ atom. In the third F1- site, F1- is bonded in a bent 120 degrees geometry to two Ag+2.67+ atoms. In the fourth F1- site, F1- is bonded in a distorted single-bond geometry to two Ag+2.67+ atoms.},
doi = {10.17188/1272341},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}