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Title: Materials Data on RbU2SbS8 by Materials Project

Abstract

RbU2SbS8 crystallizes in the monoclinic Cm space group. The structure is three-dimensional. Rb1+ is bonded in a 8-coordinate geometry to eight S2- atoms. There are a spread of Rb–S bond distances ranging from 3.34–3.59 Å. U6+ is bonded in a 8-coordinate geometry to eight S2- atoms. There are a spread of U–S bond distances ranging from 2.72–2.86 Å. Sb3+ is bonded in a see-saw-like geometry to four S2- atoms. There are two shorter (2.46 Å) and two longer (2.71 Å) Sb–S bond lengths. There are five inequivalent S2- sites. In the first S2- site, S2- is bonded in a 4-coordinate geometry to one Rb1+, two equivalent U6+, and one S2- atom. The S–S bond length is 2.07 Å. In the second S2- site, S2- is bonded in a 4-coordinate geometry to one Rb1+, two equivalent U6+, and one S2- atom. In the third S2- site, S2- is bonded in a distorted rectangular see-saw-like geometry to one Rb1+, two equivalent U6+, and one Sb3+ atom. In the fourth S2- site, S2- is bonded in a 4-coordinate geometry to one Rb1+, two equivalent U6+, and one Sb3+ atom. In the fifth S2- site, S2- is bonded in a 4-coordinate geometry to onemore » Rb1+, two equivalent U6+, and one Sb3+ atom.« less

Authors:
Publication Date:
Other Number(s):
mp-559405
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Collaborations:
MIT; UC Berkeley; Duke; U Louvain
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; RbU2SbS8; Rb-S-Sb-U
OSTI Identifier:
1270846
DOI:
https://doi.org/10.17188/1270846

Citation Formats

The Materials Project. Materials Data on RbU2SbS8 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1270846.
The Materials Project. Materials Data on RbU2SbS8 by Materials Project. United States. doi:https://doi.org/10.17188/1270846
The Materials Project. 2020. "Materials Data on RbU2SbS8 by Materials Project". United States. doi:https://doi.org/10.17188/1270846. https://www.osti.gov/servlets/purl/1270846. Pub date:Sat Jul 18 00:00:00 EDT 2020
@article{osti_1270846,
title = {Materials Data on RbU2SbS8 by Materials Project},
author = {The Materials Project},
abstractNote = {RbU2SbS8 crystallizes in the monoclinic Cm space group. The structure is three-dimensional. Rb1+ is bonded in a 8-coordinate geometry to eight S2- atoms. There are a spread of Rb–S bond distances ranging from 3.34–3.59 Å. U6+ is bonded in a 8-coordinate geometry to eight S2- atoms. There are a spread of U–S bond distances ranging from 2.72–2.86 Å. Sb3+ is bonded in a see-saw-like geometry to four S2- atoms. There are two shorter (2.46 Å) and two longer (2.71 Å) Sb–S bond lengths. There are five inequivalent S2- sites. In the first S2- site, S2- is bonded in a 4-coordinate geometry to one Rb1+, two equivalent U6+, and one S2- atom. The S–S bond length is 2.07 Å. In the second S2- site, S2- is bonded in a 4-coordinate geometry to one Rb1+, two equivalent U6+, and one S2- atom. In the third S2- site, S2- is bonded in a distorted rectangular see-saw-like geometry to one Rb1+, two equivalent U6+, and one Sb3+ atom. In the fourth S2- site, S2- is bonded in a 4-coordinate geometry to one Rb1+, two equivalent U6+, and one Sb3+ atom. In the fifth S2- site, S2- is bonded in a 4-coordinate geometry to one Rb1+, two equivalent U6+, and one Sb3+ atom.},
doi = {10.17188/1270846},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}