U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on K2Cd(AuS)4 by Materials Project
Abstract
K2Cd(AuS)4 crystallizes in the orthorhombic Ibam space group. The structure is three-dimensional. K1+ is bonded in a 8-coordinate geometry to two equivalent Au1+ and six equivalent S2- atoms. Both K–Au bond lengths are 3.57 Å. There are a spread of K–S bond distances ranging from 3.33–3.47 Å. There are two inequivalent Au1+ sites. In the first Au1+ site, Au1+ is bonded in a 2-coordinate geometry to two equivalent K1+ and two equivalent S2- atoms. Both Au–S bond lengths are 2.34 Å. In the second Au1+ site, Au1+ is bonded in a distorted linear geometry to two equivalent S2- atoms. Both Au–S bond lengths are 2.34 Å. Cd2+ is bonded in a 4-coordinate geometry to four equivalent S2- atoms. All Cd–S bond lengths are 2.66 Å. S2- is bonded in a 6-coordinate geometry to three equivalent K1+, two Au1+, and one Cd2+ atom.
- Publication Date:
- Other Number(s):
- mp-557832
- DOE Contract Number:
- AC02-05CH11231
- Research Org.:
- LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- Collaborations:
- The Materials Project; MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE; Au-Cd-K-S; K2Cd(AuS)4; crystal structure
- OSTI Identifier:
- 1270036
- DOI:
- https://doi.org/10.17188/1270036
Citation Formats
Materials Data on K2Cd(AuS)4 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1270036.
Materials Data on K2Cd(AuS)4 by Materials Project. United States. doi:https://doi.org/10.17188/1270036
2020.
"Materials Data on K2Cd(AuS)4 by Materials Project". United States. doi:https://doi.org/10.17188/1270036. https://www.osti.gov/servlets/purl/1270036. Pub date:Thu Jul 23 00:00:00 EDT 2020
@article{osti_1270036,
title = {Materials Data on K2Cd(AuS)4 by Materials Project},
abstractNote = {K2Cd(AuS)4 crystallizes in the orthorhombic Ibam space group. The structure is three-dimensional. K1+ is bonded in a 8-coordinate geometry to two equivalent Au1+ and six equivalent S2- atoms. Both K–Au bond lengths are 3.57 Å. There are a spread of K–S bond distances ranging from 3.33–3.47 Å. There are two inequivalent Au1+ sites. In the first Au1+ site, Au1+ is bonded in a 2-coordinate geometry to two equivalent K1+ and two equivalent S2- atoms. Both Au–S bond lengths are 2.34 Å. In the second Au1+ site, Au1+ is bonded in a distorted linear geometry to two equivalent S2- atoms. Both Au–S bond lengths are 2.34 Å. Cd2+ is bonded in a 4-coordinate geometry to four equivalent S2- atoms. All Cd–S bond lengths are 2.66 Å. S2- is bonded in a 6-coordinate geometry to three equivalent K1+, two Au1+, and one Cd2+ atom.},
doi = {10.17188/1270036},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}