Materials Data on LiC2S2N(O2F3)2 by Materials Project
Abstract
LiN(CF3SO2)2 crystallizes in the orthorhombic Pccn space group. The structure is one-dimensional and consists of four ammonia molecules; eight fluoroform molecules; and two Li(SO2)2 ribbons oriented in the (0, 1, 0) direction. In each Li(SO2)2 ribbon, Li1+ is bonded in a tetrahedral geometry to four O2- atoms. There are two shorter (1.98 Å) and two longer (2.03 Å) Li–O bond lengths. S2+ is bonded in a bent 120 degrees geometry to two O2- atoms. Both S–O bond lengths are 1.45 Å. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded in a bent 120 degrees geometry to one Li1+ and one S2+ atom. In the second O2- site, O2- is bonded in a bent 150 degrees geometry to one Li1+ and one S2+ atom.
- Authors:
- Publication Date:
- Other Number(s):
- mp-557395
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Collaborations:
- MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE
- Keywords:
- crystal structure; LiC2S2N(O2F3)2; C-F-Li-N-O-S
- OSTI Identifier:
- 1269820
- DOI:
- https://doi.org/10.17188/1269820
Citation Formats
The Materials Project. Materials Data on LiC2S2N(O2F3)2 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1269820.
The Materials Project. Materials Data on LiC2S2N(O2F3)2 by Materials Project. United States. doi:https://doi.org/10.17188/1269820
The Materials Project. 2020.
"Materials Data on LiC2S2N(O2F3)2 by Materials Project". United States. doi:https://doi.org/10.17188/1269820. https://www.osti.gov/servlets/purl/1269820. Pub date:Thu Apr 30 00:00:00 EDT 2020
@article{osti_1269820,
title = {Materials Data on LiC2S2N(O2F3)2 by Materials Project},
author = {The Materials Project},
abstractNote = {LiN(CF3SO2)2 crystallizes in the orthorhombic Pccn space group. The structure is one-dimensional and consists of four ammonia molecules; eight fluoroform molecules; and two Li(SO2)2 ribbons oriented in the (0, 1, 0) direction. In each Li(SO2)2 ribbon, Li1+ is bonded in a tetrahedral geometry to four O2- atoms. There are two shorter (1.98 Å) and two longer (2.03 Å) Li–O bond lengths. S2+ is bonded in a bent 120 degrees geometry to two O2- atoms. Both S–O bond lengths are 1.45 Å. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded in a bent 120 degrees geometry to one Li1+ and one S2+ atom. In the second O2- site, O2- is bonded in a bent 150 degrees geometry to one Li1+ and one S2+ atom.},
doi = {10.17188/1269820},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Thu Apr 30 00:00:00 EDT 2020},
month = {Thu Apr 30 00:00:00 EDT 2020}
}
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